In the drinking water treatment processes, the optimization of the treatment is an issue of particular concern. In general, the process consists of many units as settling, coagulation, flocculation, sedimentation, filtration and disinfection. The optimization of the process consists of some measures to decrease the managing and monitoring expenses and improve the quality of the produced water. The objective of this study is to provide water treatment operators with methods and practices that enable to attain the most effective use of the facility and in consequence optimize the cubic meter price of the treated water. This paper proposes a review on optimization of drinking water treatment process by analyzing all of the water treatment units and gives some solutions in order to maximize the water treatment performances without compromising the water quality standards. Some practical solutions and methods are performed in the water treatment plant located in the middle of Morocco (Meknes).
Optimization Coagulation Process Turbidity Removal Water Treatment1. Introduction
The demand on water supply is increasing over the last century due to improved lifestyle, industrial development and population growth. This increased demand is facing a paradox to produce treated water with high quality at lower cost. In order to reduce the water cost, it is very important to optimize the operating expenses in the water treatment plant (power, chemicals, operator’s expenses…) and many measures should be performed in this vision.
The optimization of water treatment plant is not a disciplinary to maximize the treatment objective and minimize the cost of the water produced. But it consists of understanding the functioning of the treatment plant and treasure the experience of the operators in dealing with all treatment process related to different aspects.
This paper addresses the problem of optimizing of the conventional drinking water plant and proposes some practical to reach this goal. This paper is organized as fellows. After an introduction of the objective of this study, the water treatment operation is described in Section 2. Review on optimization of conventional drinking water treatment plant is discussed in Section 3. In Section 4, some practical methods are explained.
2. Water Treatment Operation
Meknes region is located in the middle of Moroccan Kingdom, has a Mediterranean climate with continental influences. The temperature shifts from cool and cold in winter to hot days in the summer months of June - September. The agriculture and industry are the mean activities in the region.
This study was developed in a water treatment plant located in Meknes, whose source is two big springs Bittit (630 l/s) and Ribaa (400 l/s). The quality of water, produced by the spring, changes according to the rainfall in the region. Sometimes, it can be affected by the snow in the Atlas Mountains. The treatment water plant, as part of other water resources, water to more than 700,000 inhabitants of Meknes city, and it has a nominal capacity of 600 l/s of treated water. This water treatment plant is chosen regarding to the variation of the raw water turbidity and because of the availability of data. Figure 1 presents a schematic overview of the various operations necessary to treat the water.
Many measurements of variables recorded by streaming current detectors such as: turbidity level, PH, conductivity, temperature is needed to carry out the jars test in order to determine the optimal dose of the aluminum sulfate. Table 1 shows the raw water variables used in this study, and they present the following variation intervals.
Simplified synopsis of the water treatment plant
Statistical summary of raw water conditions from 01/01/2013 to 31/12/2015 (ONEE, 2015)
Variables
Min
Max
Turbidity: Bittit (NTU)
1.7
850
Turbidity: Ribaa (NTU)
1.62
960
PH
6.80
7.74
Temperature: (˚C)
14
24.70
Conductivity micro s/cm
509
624
The variation of PH, conductivity and temperature from 01/01/2013 to 31/12/2015 is given by Figures 2(a)-(c).
In the rainfall period, the turbidity of raw water changes from time to time as shown in the graph below, the turbidity of the raw water can increase to reach levels more than 500 NTU as shown in Figure 3.
Evolution of PH. (a) conductivity in micro S/cm; (b) and temperature in ˚C; (c) of raw water from 01/01/2013 to 31/12/2015.
Statistical data of turbidity level of the spring’s water from 01/01/2013 to 31/12/2015 (ONEE, 2015).
Turbidity levels distribution from 2009 to 2015 (number of days per turbidity level)
Year
Number of days
Total
Turbidity less or equal than 5 NTU
Turbidity more than 5and less or equal than 10 NTU
Turbidity more than 10 and less or equal than 20 NTU
Turbidity more than 20 and less or equal than 40 NTU
Turbidity more than 40 NTU
2009
147
60
101
34
23
365
2010
0
0
113
148
104
365
2011
0
132
144
59
30
365
2012
301
38
17
5
5
366
2013
260
74
23
8
0
365
2014
247
62
32
20
4
365
2015
184
132
34
10
5
365
Total
1139
498
464
284
171
2556
Aggregated data
1139
1637
2101
2385
2556
Percentage
45%
19%
18%
11%
7%
Percentage of Aggregated data
45%
64%
82%
93%
100%
However, the turbidity level is less than 10 NTU this three last years (2013, 2014 and 2015) for more than 88% of the year and more than 64% of the year (1637/2556 days); the turbidity is less than 10 NTU for the six last years as shown by Table 2.
Table 3 gives the max and min of raw water turbidity by month from 2013 to 2015.
The chemicals used in the water treatment process consume about 50% the total operating expenses of the water treatment. The energy cost is between 10% and 15% related to the total cost in 2013, 2014 and 2015. Figure 4 gives the operations expenses of the water treatment plant in the three last years.
In addition, used as coagulant, the aluminum sulfate (SA) consumption is more than 65% of the total chemicals consumption in the water treatment plant. Le polyelectrolyte (Poly) consumption is less than 10% and the chlorine is between 16% and 26% of the total chemicals used in the water treatment plant according to the water quality as shown by Figure 5.
3. Review on Optimization of Drinking Water Treatment Plant
In order to remove turbidity and contaminants from raw water, the treatment comprises many steps as the settling, aeration, coagulation, sedimentation, filtration and disinfection. The optimization of water treatment plant
Statistical data of turbidity min and max (NTU) measured in 2013, 2014 and 2015 per month (ONEE, 2015)
Year: 2013
Bittit Spring
Ribaa Spring
Month
min
max
min
max
January
3.70
18.95
10.00
50.00
February
4.50
19.00
3.95
20.65
March
4.95
98.40
4.50
136.66
April
6.40
21.95
4.90
32.77
May
3.93
6.30
3.80
5.30
June
3.72
4.40
3.34
4.89
July
3.30
4.33
2.92
3.62
August
3.00
3.80
2.70
3.46
September
3.10
4.64
2.68
4.15
October
2.90
3.99
2.46
3.62
November
2.70
7.44
2.90
10.00
December
3.07
4.23
2.60
3.95
Year: 2014
Bittit Spring
Ribaa Spring
min
max
min
max
January
3.06
81.69
3.00
120.66
February
6.48
128.00
5.93
78.90
March
4.86
6.91
3.90
5.65
April
4.30
4.90
3.30
4.19
May
3.17
4.77
2,48
3.37
June
3.00
3.86
2.60
2.87
July
2.36
4.50
2.16
2.49
August
1.74
4.20
1.88
2.28
September
1.80
3.50
1.64
1.90
October
1.89
4.20
1.67
11.64
November
1.80
55.50
1.68
69.29
December
6.57
197.50
5.06
235.89
Year: 2015
Bittit Spring
Ribaa Spring
min
max
min
max
January
5.09
63.10
3.96
61.59
February
6.33
38.52
3.98
19.45
March
4.97
6.27
3.26
4.64
April
3.65
5.60
2.80
3.76
May
3.50
5.23
2.68
3.06
June
3.40
4.52
2.61
3.19
July
2.80
4.75
2.40
3.60
August
2.60
3.26
2.45
2.74
September
2.70
128.45
2.35
86.63
October
4.35
669.71
3.22
524.03
November
6.76
17.18
3.99
13.19
December
7.18
9.54
3.42
4.02
Operations expenses of the water treatment plant in 2013, 2014 and 2015 (ONEE, 2015)
Percentage of chemicals expenses consumed by the water treatment plant in 2013, 2014 and 2015 (ONEE, 2015)
concerns the different steps of the process. The main goals are to:
・ Achieve the chemical cost performance.
・ Manage and control the energy consumption.
・ Reduce the water wastes.
Many research and studies are performed in order to increase the water treatment plant performances. In this section, one aspect related to the optimization is treated which is the coagulant consumption.
3.1. Coagulant and Coagulant Aid
In the water treatment plant, colloidal particles are separated by means of a chemical coagulation process: consisting in the charge destabilization of the suspended particles by adding coagulant. The coagulant used is aluminum sulfate; it is the most widely used coagulant in Morocco as well as many other countries in the drinking water industry. It is mainly used because of its effectiveness, accessibility and low price. As a common practice, aluminum sulfate is applied according to the jars test results. The main difficulty is how to optimize the aluminum sulfate dosage related to raw water characteristics by using other cheaper products. Some attempts have been made to improve the effectiveness of the aluminum sulfate or to substitute this coagulant by another natural, available and cheaper. Finding of various coagulation processes have been reported in literature. Some of these include; studying the effect of using the bentonite on the coagulation in the treatment of low turbidity [1] . Also, Mukheled (2012) [2] used Date seeds and Pollen Sheath as coagulant to treat different levels of turbidity (75, 150 and 300 NTU). Eman et al. (2010) [3] tried Moringa Oleifera seed in the coagulation process to treat low turbid water in Malaysia. However, Aho et al. (2012) [4] highly recommended the use of this natural coagulant in the domestic turbid water purification in Nigeria. Other natural coagulants are proposed as an important alternative in the water treatment plant. The coagulants are from plant origin such as nirmali seed and maize [5] , cassia angustifolia seed [6] , mesquite bean and cactus latifaria [7] , chestnut and acorn [8] , Cocciniaindica fruit mucilage [9] and from different leguminous species [10] . Also, the Bhindi seed, Methi, Beheda, Guar seeds and Drum stick can be used as coagulant in 100 to 1200 NTU turbid water range with remarkable percentage removal from 70% to 93% [11] . In the other hand, Cocciniaindica, Strychnospotatorum and Cactus opuntia were used as natural coagulant and improved the quality of the filtered water [12] . Those natural products have coagulating activity in the treatment of turbid water and can be used as coagulant or as coagulant aid with other synthetic and industrial coagulants (aluminum sulfate…) in order to reduce the coagulant consumption in the water treatment plant [13] .
3.2. Coagulant Control and Monitoring
As a common practice, aluminum sulfate is applied according to the jars test results. The problem is to determine the optimal dose of aluminum sulfate related to raw water characteristics. Both manual and automatic methods are used to predict optimum coagulant dose [14] [15] . Automatic method is ensured by streaming current detectors [16] . However, manual method is consisting to determine the quantity of the coagulant to apply experimentally and based on the jar test results. Jar test involves taking a raw water samples and applying different quantities of coagulant to each sample [15] . After a short period of time, each sample is assessed for water quality and the dosage that produces the optimal result used a set point. This operation should be repeated by the operators each time when the quality of raw water changes. The aluminum sulfate is the compound likely to be mathematically modeled and therefore its value can be estimated according to the data available in the treatment plant. The optimization of using the coagulant is very interesting approach because under dosing of coagulant can lead to poor quality drinking water while too much coagulant leads to many operating problems (less efficient filtration and sedimentation, PH), healthy problems and can increase the cost of treated water.
Some attempts have been made to model the relationships between raw water quality characteristics and the optima coagulant dosage rate.
4. Practical Methods of Water Treatment Plant Optimization4.1. Understanding of the Water Treatment Process
The understanding of the water treatment functioning is a very important step on the performances optimization program. A systematic gathering of information about plant performances are need such as:
・ Data trending and analysis.
・ Check plant design criteria against actual and the controlling operations to improve the plant performances.
・ Track chemical dosing and use indicators.
・ Field measurements and visual observation.
・ Collaboration of operators (quality water operators, maintenance team and managing operator).
・ Plant specific operating guidelines and procedures.
・ Accuracy and control of the on-line measurement devices.
4.2. The Aluminum Sulfate Consumption
The sludge produced in the settling step of the treatment process is used not only to reduce the aluminum sulfate dose and the sludge volume but also in order to improve the water quality.
A standard jar test apparatus equipped with six paddles rotating in a set of six beakers is used to simulate coagulation, flocculation and sedimentation processes. At the first, Control experiments for coagulation tests are performed in order to determine the optimal dose of the aluminum sulfate in normal conditions. The selected level of turbid water (1 L) is filled into the beakers and various doses in the range from 10 to 100 mg/l of sludge and the aluminum sulfate according to the results of the first jar test determining the optimal dose of the inorganic coagulant in normal conditions are separately added in the beakers and mixed rapidly (300 rpm) for one minute. The mixing speed was then reduced to 40 rpm for 20 minutes. Then the stirrer is turned off and the suspensions are allowed to settle for different periods of time ranging from 30 to 120 minutes under quiescent conditions. After each period of settling time, supernatant samples of each beaker in the jar test is withdrawn from located 10 cm below the water level and residual turbidity is measured.
Standard Jar test experiments were performed to determine the optimal dose of aluminum sulfate. A set of experiments were performed using jar test to investigate the optimal dose of sludge to add in order to improve the quality of water.
The sludge produced by the treatment plant and used with the aluminum sulfate improves the turbidity removal percentage and achieve good removal efficiencies. The maximum value of turbidity removal at turbidity of 10 NTU is 98.41 corresponding to the optimum dose of sludge of 35 mg/l.
A set of experiments is performed using the optimal sludge dose obtained from the experiments below (35 mg/l) while the aluminum sulfate was changed from 0 to 10 mg/l. Figure 6 shows the effect of aluminum sulfate and sludge dose under various settling time on turbidity removal.
Table 4 gives the results of turbidity removal percentage using aluminum sulfate only, optimal dose of AS and sludge and the optimal dose of sludge and the proposed dose of AS.
The results show that the sludge used as coagulant aid with the aluminum sulfate improve not only the water
Effect of Aluminum sulfate doses (mg/l) and sludge dose (35 mg/l) under various settling time (ST) on turbidity removal percent (%)
Turbidity removal percentage (%) using AS and sludge at settling time of 60 minutes
Turbidity = 10 NTU
Initial turbidity
10
Optimal dose of Aluminum sulfate (mg/l) (1)
10
Optimal dose of sludge (mg/l) used within AS (2)
35
Dose of AS (mg/l) proposed to be used with optimal dose of sludge (3)
6
Turbidity removal percentage using only AS (1)
96.71%
Turbidity removal percentage using AS and sludge as coagulant aid (1) + (2)
97.14%
Turbidity removal percentage using optimal dose of sludge and AS (2) + (3)
97.56%
quality produced by the treatment plant (turbidity removal percentage from 96.71% to 97.56% but also it can be used to reduce the aluminum sulfate dose in the coagulation process by 40%.
4.3. Chlorination
The chlorine is the second chemical which impacts the cost of the treated water. The optimization of the consumption of this chemical can reduce the cost of the water produced by the water treatment plant. Some measures should be taken such as:
・ On-line and laboratory instruments verification.
・ Disinfection data handling and reporting.
・ Verification of on-line chlorine residual analyzes.
・ Verification of the performances of the on-line instruments with a grab sample measurement at least once every week.
・ Respect of the manufacturer’s instructions for instrument calibration.
・ Completion of grab sample verification after changing reagents or doses or doing any other maintenance operations on the instrument.
・ Incorporation of all manufacturer recommended instrument maintenance.
・ Using a portable kit to verify performances of on-line instruments.
4.4. Energy
The energy consumed by the water treatment plant can be optimized by adopting many measures such as:
・ Using of variables speed drives on pump motors.
・ Lighting controls upgrade.
・ The preventive maintenance of different equipment and motors.
・ The replacement of existing pumps and motors by more efficient pumps and motors.
The implementation of such measures results in annual electric savings of more than 6% of the energy consumed by the water treatment plant.
5. Conclusion
This paper has presented some results concerning many practical methods used in the management of the water treatment plant, the use of sludge as coagulant aid with the aluminum sulfate in the water treatment plant. The sludge improves the quality of the produced water by increasing the coagulation efficiency and the aluminum sulfate dosage is decreased. The sludge volume is reduced and subsequently sludge management costs. The coagulation process is optimizing and this approach offers several significant economics and operational benefits such as it minimizes the aluminum dose required to 40%, reduces the sludge volume produced by the treatment plant and decreases the residual turbidity of the water. These advantages are very important not only for process economy through reducing the cost of treatment but also in the management of the sludge volume. Therefore, it is reasonable to consider this approach to be applied in the treatment plant for water with similar turbidity level. Also, the chlorine and energy consumption can be reduced in order to optimize the water treatment plant performances.
Cite this paper
Mohamed Farhaoui,Mustapha Derraz, (2016) Review on Optimization of Drinking Water Treatment Process. Journal of Water Resource and Protection,08,777-786. doi: 10.4236/jwarp.2016.88063
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