Stream sediment geochemistry remains a versatile tool in exploration especially in regions where knowledge of the primary mineralization is lacking and the exploration activities are still at reconnaissance stage. In this study, we investigate the concentrations of gold and associated elements in stream sediment samples from the Vaimba-Lidi drainage system in northern Cameroon; a relatively remote area where alluvial gold is worked locally, and exploration activities are at early stage. The main river and its principal first and second order tributaries were sampled, panned for gold grain recovery and the 100 μm size fraction analyzed for Au by fire assay with Ni finish. A suite of other elements were analyzed for by inductively coupled plasma mass spectrometry (ICP-MS). Gold grades estimated by the panning and weighing technique rarely exceed1 g/t while the Au concentrations from chemical analysis range from 3.0 to 354.0 ppm. The spatial distribution of gold and all the other elements are presented as point symbol maps and the data analyzed using multivariate statistics. From the principal component analysis (PCA), the As-Mo-W-Ag as well as the Au-Zn factors point to the presence of primary hydrothermal gold-sulphide mineralization in the area and this can be further investigated. These results highlight the importance of multielement analysis and multivariate statistical interpretation of sediment geochemical data in inferring the nature of the underlying primary mineralization in any region.
Gold exploration using stream sediments commonly relies on two combined approaches: the proportion of gold grains in the heavy mineral fraction and the bulk major and/or trace element content of the samples. For the heavy mineral fraction, samples are often weighed on the field, sieved and the recovered gold grains weighed. This approach gives a first pass indication of the gold potential within the catchments area and assists in delineating areas for further investigation. A significant aspect of research is to find out if areas of high gold grades determined by the panning and weighing method correlate positively with areas of high gold concentrations determined by bulk sample geochemistry. Also, the spatial display of stream sediment geochemical data as well as the statistical treatment of the data can unravel element associations that are relevant to primary exploration in the region. These associations are also useful in speculating on the source region lithology, geological processes and the nature of the primary (rock-hosted) mineralization, if any is present [e.g., 1-3].
In exploring for gold using stream sediments, it is often more effective to analyse for the spatial distribution of a suite of elements than simply looking at gold alone. Gold usually occurs in association with other elements such as Cu, As, Zn, Fe, Pb, W (when the gold is associated with chalcopyrite, arsenopyrite, sphalerite, pyrite, galena and scheelite, respectively, in hydrothermal veins) [4,5]. Therefore, to obtain any meaningful interpretation of geochemical data from stream sediments, the data must be handled with the appropriate techniques which will permit the differentiation of the various processes that lead to their formation and modification in the primary and secondary environments. This is often achieved by using various multivariate statistical methods such as factor and cluster analysis together with two-dimensional single element point symbol maps [e.g., 5-9] for elemental spatial distribution display.
In Cameroon, alluvial gold exploitation commenced in the early 1940s and continues to date although records declaring the output of this activity during this period are unavailable. Most of the small-scale alluvial gold mining operations are located in the Lom Basin of the Betare Oya district (Figure 1) and to the south of it extending to the Batouri district [4]. The region extending northwards from the Betare Oya district has witnessed little or no exploration works. With the fear that rising waters of the Lagdo dam (Figure 2(a)) might flood the entire region, a
new and aggressive approach to exploration in this little known (in economic geology terms) northern part of Cameroon with regards to Au mineralization is witnessing a heightened level of attention from both private investment groups and public research institutions like the Universities. This contribution falls within this context and examines part of the drainage system that empties into the Lagdo dam.
Previous published works on gold mineralization in Cameroon have examined the style of hydrothermal vein mineralization [4], the morphology and microchemistry of gold grains [11], the alteration and gold grade variation in wall rock in the Lom series [12] as well as geophysical delineation of favourable host structures [13]. Stream sediments have by and large received little attention. In an attempt to open new gold potentials in the northern part of the country, we designed a stream sediment survey targeting the Vaimba-Lidi drainage system in the north of Cameroon (Figure 2(b)) that flows into the Lagdo dam. Here we show that areas of high gold grade determined by the weighing and panning method are differrent from those determined by bulk sample geochemistry, suggesting that gold might have different source lithologies in the area and occur in different forms. This may also reflect the presence of gold nuggets in the >100 μm size fraction. Also we show using multivariate statistics that gold is its own best pathfinder element although the As-Mo-W association suggests the presence of sulphide-dominated hydrothermal mineralization in the catchment area. The other trace element associations show that granitic rocks underlie most of the catchment and we speculate that a primary granite-related gold mineral system is the princepal controlling factor. These results are of more than local significance and add to the global discourse on the use of stream sediments for gold exploration in humid tropical settings.
2. LOCATION OF STUDY AREA AND REGIONAL GEOLOGICAL FRAMEWORK
The Vaimba-Lidi drainage system is part of the wider Benue basin river system in the north of Cameroon (Figure 2). The Benue basin river system has a NE-SW orientation and extends from southern Chad across northern Cameroon into northern Nigeria and represents one of the major drainage systems in West Africa. Farther downstream in Nigeria, the Benue merges with river Niger that empties into the Atlantic Ocean farther south. The area of study lies between longitudes 14˚10'E and 14˚50'E and latitudes 8˚30'N and 8˚60'N with spot heights that do not exceed 200 m above sea level.
The Vaimba-Lidi river system (Figure 2) drains an area dominated by volcano-sedimentary rocks that constitute part of the Pan-African mobile belt sandwiched between the Congo Craton to the south (Figure 1) and the West African Craton to the west. Excellent reviews
on this regional picture are provided in [14-18]. Petrologic and isotopic studies have shown that this Pan-African geotectonic unit in Cameroon can be subdivided into three groups, namely the Yaoundé Group (southern Cameroon), the Adamawa domain (central Cameroon) and the Poli Group (northern Cameroon). The study area is part of the Poli group with volcano-sedimentary lithologies reminiscent of an early Neoproterozoic back-arc basin formed between 830 and 665 Ma [19,20]. These sediments were then subjected to deformation, metamorphism, and intensive plutonism between 630 and 580 Ma [19,21-24]. Stratigraphically, the rock units have a very poor resolution since they are interleaved and strongly deformed [22,23] although it is widely believed that there is an alternation between metavolcanic and metasedimentary rocks. In this area volcanogenic clastic rocks (mainly tuffs) and reworked clastic rocks (metagreywackes) with conglomerate layers are common [25]. Rhyolite and tholeiitic basalts are the rock types that make up the metavolcanic unit. Granitic intrusions, mainly of Pan-African age, are widespread in the area and their emplacement was controlled by the development of late strike slip faults that crosscut early gently folded structures with E-W-trending axial surfaces. These plutons are calc-alkaline to alkaline in compositions [19].
3. MATERIALS AND METHODS
Fifty one (51) active stream sediment samples were collected at various points within the drainage basin (as shown in Figure 2(b)) defining an area ~10.4 km2. First and second order tributaries as well as the main Lidi and Vaimba rivers were sampled. Samples from second order tributaries were collected at suitable sites above their confluence point. In the field, homogenized samples were in situ sub divided into two fractions and weighed. In order to obtain Au grade by the panning and weighing method, one fraction from each sampling point was first weighed, then panned and later in the camp gold grains in the dried heavy mineral concentrate were handpicked under a binocular microscope and weighed. This gave an indication of the gold grade in each sample and the grade variation thus determined is presented in Figure 3. The remaining fraction was wet sieved in the field and the 100 μm size fraction retained for further laboratory geochemical analysis.
In the laboratory, each 100 μm size fraction was sub divided into two subsets. Trace element concentrations were determined from one subset by ICP-MS and Au from the other by fire assay with a nickel finish. These subsets were first crushed and milled to fine powder. With the ICP-MS method, an argon plasma which reaches working temperatures of 6000˚C - 8000˚C was generated by radio frequency excitation. Solutions prepared from 10 g of each of the samples was fused with lithium-borate, metaborate and then leached with 30% dilute nitric acid (HNO3) were injected into the plasma. This solution was excited and produced analyte ions
which were separated and measured by mass spectrometry (MS). To measure Au concentration by the fire assay method 10 g of an aliquot powdered sample was mixed with soda ash (sodium carbonate). To this mixture, Ni collector was added in solution. The well mixed material was then fired at temperatures ranging from 1100˚C to 1200˚C in a crucible. As the Ni in the melt settled to the bottom of the crucible, it scavenged the Au from the melt. This nickel was then collected and dissolved out leaving a tiny Au flake which was weighed (gravimetric technique).
4. RESULTS4.1. Gold Grade Estimated by the Panning and Weighing Technique
The gold grades estimated by weighing picked gold grains are generally low and erratic and only a few values exceed 1 g/t (Figure 3).
The point symbol map or spatial plot (Figure 3) shows this variation with the relatively higher Au concentrations found in the head water areas of river Vaimba which flows from east to west (Figure 3). The grade decreases downstream along this river (Figure 3) away from the catchment area. All gold grades for samples collected along the Lidi River and its principal tributaries as well as the Bidjou River were below 1 g/t (Figure 3).
4.2. Geochemical Analysis
As stated before, a total of 51 samples were analysed for a whole suite of elements and only the 19 elements with concentrations above the detection limit are reported here. The raw data set can be obtained upon request from the corresponding author. These geochemical data are summarized in Table 1. To investigate the inter element relationship, the raw data were log transformed and a Pearson’s correlation matrix was computed for the elements (Table 2). From Table 2 Au has a relatively high correlation value of 0.43 only with Zn. Other element pairs with high positive r values include Y-Nb, Cu-Y, Cu-Nb, La-Ce. A few elements such as Cu-Ba and Cu-Sr have very low correlation coefficients. To further investigate these element associations, the data were subjected to principal component factor analysis [26].
Five factors or components were generated (Table 3) with each representing a cluster of interrelated elements within the data set. These five factors are as follows:
Factor 1: Y-Nb-Cu-Zr
Factor 2: Sr-Sb-Ba-La-Ce-Pb
Factor 3: As-Mo-W-Ag
Factor 4: Cd
Factor 5: Au-Zn.
The association of Au and Zn define a factor on its own pointing to possible sphalerite mineralization associated with gold in the underlying rock. Factor 3 is a
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