<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd">
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article">
 <front>
  <journal-meta>
   <journal-id journal-id-type="publisher-id">
    acs
   </journal-id>
   <journal-title-group>
    <journal-title>
     Atmospheric and Climate Sciences
    </journal-title>
   </journal-title-group>
   <issn pub-type="epub">
    2160-0414
   </issn>
   <issn publication-format="print">
    2160-0422
   </issn>
   <publisher>
    <publisher-name>
     Scientific Research Publishing
    </publisher-name>
   </publisher>
  </journal-meta>
  <article-meta>
   <article-id pub-id-type="doi">
    10.4236/acs.2024.144029
   </article-id>
   <article-id pub-id-type="publisher-id">
    acs-136761
   </article-id>
   <article-categories>
    <subj-group subj-group-type="heading">
     <subject>
      Articles
     </subject>
    </subj-group>
    <subj-group subj-group-type="Discipline-v2">
     <subject>
      Earth 
     </subject>
     <subject>
       Environmental Sciences
     </subject>
    </subj-group>
   </article-categories>
   <title-group>
    Cross-Correlation between Global Temperature and Atmospheric CO
    <sub>2</sub> with a Temperature-Leading Time Lag
   </title-group>
   <contrib-group>
    <contrib contrib-type="author" xlink:type="simple">
     <name name-style="western">
      <surname>
       Masaharu
      </surname>
      <given-names>
       Nishioka
      </given-names>
     </name>
    </contrib>
   </contrib-group> 
   <aff id="affnull">
    <addr-line>
     aRetired, Chicago, USA
    </addr-line> 
   </aff> 
   <pub-date pub-type="epub">
    <day>
     30
    </day> 
    <month>
     08
    </month>
    <year>
     2024
    </year>
   </pub-date> 
   <volume>
    14
   </volume> 
   <issue>
    04
   </issue>
   <fpage>
    484
   </fpage>
   <lpage>
    494
   </lpage>
   <history>
    <date date-type="received">
     <day>
      19,
     </day>
     <month>
      September
     </month>
     <year>
      2024
     </year>
    </date>
    <date date-type="published">
     <day>
      20,
     </day>
     <month>
      September
     </month>
     <year>
      2024
     </year> 
    </date> 
    <date date-type="accepted">
     <day>
      20,
     </day>
     <month>
      October
     </month>
     <year>
      2024
     </year> 
    </date>
   </history>
   <permissions>
    <copyright-statement>
     © Copyright 2014 by authors and Scientific Research Publishing Inc. 
    </copyright-statement>
    <copyright-year>
     2014
    </copyright-year>
    <license>
     <license-p>
      This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/
     </license-p>
    </license>
   </permissions>
   <abstract>
    The temperature change and rate of CO
    <sub>2</sub> change are correlated with a time lag, as reported in a previous paper. The correlation was investigated by calculating a correlation coefficient r of these changes for selected ENSO events in this study. Annual periodical increases and decreases in the CO
    <sub>2</sub> concentration were considered, with a regular pattern of minimum values in August and maximum values in May each year. An increased deviation in CO
    <sub>2</sub> and temperature was found in response to the occurrence of El Niño, but the increase in CO
    <sub>2</sub> lagged behind the change in temperature by 5 months. This pattern was not observed for La Niña events. An increase in global CO
    <sub>2</sub> emissions and a subsequent increase in global temperature proposed by IPCC were not observed, but an increase in global temperature, an increase in soil respiration, and a subsequent increase in global CO
    <sub>2</sub> emissions were noticed. This natural process can be clearly detected during periods of increasing temperature specifically during El Niño events. The results cast strong doubts that anthropogenic CO
    <sub>2</sub> is the cause of global warming.
   </abstract>
   <kwd-group> 
    <kwd>
     Global Warming
    </kwd> 
    <kwd>
      Thermally-Induced CO
     <sub>2</sub>
    </kwd> 
    <kwd>
      Soil Respiration
    </kwd> 
    <kwd>
      Cross-Correlation Coefficient
    </kwd> 
    <kwd>
      Time Lag
    </kwd> 
    <kwd>
      El Niño
    </kwd>
   </kwd-group>
  </article-meta>
 </front>
 <body>
  <sec id="s1">
   <title>1. Introduction</title>
   <p>Murry Salby analyzed the change in temperature (ΔT) and the change rate of the CO<sub>2</sub> concentration (rco<sub>2</sub>) and suggested that the change rate of the CO<sub>2</sub> concentration (drco<sub>2</sub>/dt) can be expressed as Equation (1) <xref ref-type="bibr" rid="scirp.136761-1">
     [1]
    </xref> <xref ref-type="bibr" rid="scirp.136761-2">
     [2]
    </xref>:</p>
   <p>
    <math display="inline" xmlns="http://www.w3.org/1998/Math/MathML"> <mrow> 
      <mrow> 
       <mrow> 
        <mi>
          d 
        </mi> 
        <mi>
          r 
        </mi> 
        <mi>
          c 
        </mi> 
        <msub> 
         <mi>
           o 
         </mi> 
         <mn>
           2 
         </mn> 
        </msub> 
       </mrow> 
       <mo>
         / 
       </mo> 
       <mrow> 
        <mi>
          d 
        </mi> 
        <mi>
          t 
        </mi> 
       </mrow> 
      </mrow> 
      <mo>
        = 
      </mo> 
      <mi>
        γ 
      </mi> 
      <mi>
        Δ 
      </mi> 
      <mi>
        T 
      </mi> 
     </mrow> 
    </math> (1)</p>
   <p>where γ is a constant, or Equation (1) is also expressed by Equation (2):</p>
   <p>
    <math display="inline" xmlns="http://www.w3.org/1998/Math/MathML"> <mrow> 
      <msub> 
       <mi>
         r 
       </mi> 
       <mrow> 
        <mi>
          C 
        </mi> 
        <msub> 
         <mi>
           O 
         </mi> 
         <mn>
           2 
         </mn> 
        </msub> 
       </mrow> 
      </msub> 
      <mo> 
      </mo> 
      <mo>
        = 
      </mo> 
      <mi>
        γ 
      </mi> 
      <munderover> 
       <mstyle mathsize="140%" displaystyle="true"> 
        <mo>
          ∫ 
        </mo> 
       </mstyle> 
       <mn>
         0 
       </mn> 
       <mi>
         t 
       </mi> 
      </munderover> 
      <mi>
        Δ 
      </mi> 
      <mi>
        T 
      </mi> 
      <mi>
        d 
      </mi> 
      <mi>
        t 
      </mi> 
     </mrow> 
    </math> (2)</p>
   <p>The major natural functions affecting drco<sub>2</sub>/dt are (1) plant photosynthesis, (2) CO<sub>2</sub> solubilization into the ocean, and (3) plant decomposition or respiration <xref ref-type="bibr" rid="scirp.136761-3">
     [3]
    </xref>. For a small temperature range, drco<sub>2</sub>/dt may be considered to be approximately proportional to the temperature change <xref ref-type="bibr" rid="scirp.136761-4">
     [4]
    </xref>:</p>
   <p>
    <math display="inline" xmlns="http://www.w3.org/1998/Math/MathML"> <mtable columnalign="left"> 
      <mtr> 
       <mtd> 
        <mrow> 
         <mrow> 
          <mi>
            d 
          </mi> 
          <mi>
            r 
          </mi> 
          <mi>
            c 
          </mi> 
          <msub> 
           <mi>
             o 
           </mi> 
           <mn>
             2 
           </mn> 
          </msub> 
         </mrow> 
         <mo>
           / 
         </mo> 
         <mrow> 
          <mi>
            d 
          </mi> 
          <mi>
            t 
          </mi> 
         </mrow> 
        </mrow> 
       </mtd> 
      </mtr> 
      <mtr> 
       <mtd> 
        <mo>
          ≒ 
        </mo> 
        <mtext>
          rate of photosynthesis 
        </mtext> 
        <mo>
          + 
        </mo> 
        <mtext>
          solubilization rate into sea 
        </mtext> 
       </mtd> 
      </mtr> 
      <mtr> 
       <mtd> 
        <mtext>
            
        </mtext> 
        <mtext>
            
        </mtext> 
        <mtext>
            
        </mtext> 
        <mtext>
            
        </mtext> 
        <mo>
          + 
        </mo> 
        <mtext>
          plant decomposition rate 
        </mtext> 
       </mtd> 
      </mtr> 
      <mtr> 
       <mtd> 
        <mo>
          ≒ 
        </mo> 
        <mi>
          γ 
        </mi> 
        <mi>
          Δ 
        </mi> 
        <mi>
          T 
        </mi> 
       </mtd> 
      </mtr> 
     </mtable> 
    </math> (3)</p>
   <p>Recent direct observations of CO<sub>2</sub> concentrations have shown that the CO<sub>2</sub> concentration steadily increases every year <xref ref-type="bibr" rid="scirp.136761-5">
     [5]
    </xref>. The change rate of the CO<sub>2</sub> concentration, drco<sub>2</sub>/dt, is the change in the CO<sub>2</sub> concentration during a predetermined time and can be expressed as an annual CO<sub>2</sub> growth rate, “ppm/year”.</p>
   <p>The annual mean CO<sub>2</sub> growth rates are reported by the National Oceanic and Atmospheric Administration (NOAA) <xref ref-type="bibr" rid="scirp.136761-6">
     [6]
    </xref>. Since 1979, NOAA satellites have been carrying instruments that measure natural microwave thermal emissions from oxygen in the atmosphere <xref ref-type="bibr" rid="scirp.136761-7">
     [7]
    </xref>. Every month, the University of Alabama in Huntsville (UAH) updates global temperature datasets from different satellites. Satellite-based temperatures, the 13-month average of lower troposphere anomaly values, and CO<sub>2</sub> growth rates were compared to evaluate Equation (1) during 1979-2022, which revealed that temperature changes and the CO<sub>2</sub> growth rate are correlated over 40 years. Therefore, Equation (1) is supported by the observed results <xref ref-type="bibr" rid="scirp.136761-8">
     [8]
    </xref>.</p>
   <p>For a short period of time, Equation (1) may be expressed as Equation (4),</p>
   <p>
    <math display="inline" xmlns="http://www.w3.org/1998/Math/MathML"> <mrow> 
      <mi>
        Δ 
      </mi> 
      <mi>
        r 
      </mi> 
      <mi>
        c 
      </mi> 
      <msub> 
       <mi>
         o 
       </mi> 
       <mn>
         2 
       </mn> 
      </msub> 
      <mo>
        ∝ 
      </mo> 
      <mi>
        Δ 
      </mi> 
      <mi>
        T 
      </mi> 
     </mrow> 
    </math> (4)</p>
   <p>(Δrco<sub>2</sub>: a change in CO<sub>2</sub> concentration).</p>
   <p>In other words, the CO<sub>2</sub> concentration is determined by temperature changes, and generally, the higher the temperature is, the higher the CO<sub>2</sub> concentration, which may be called “thermally induced CO<sub>2</sub>” <xref ref-type="bibr" rid="scirp.136761-1">
     [1]
    </xref> <xref ref-type="bibr" rid="scirp.136761-2">
     [2]
    </xref>. As temperatures change due to seasons and weather events, CO<sub>2</sub> can also change with temperature <xref ref-type="bibr" rid="scirp.136761-8">
     [8]
    </xref>. This was confirmed by ENSO events, which drive temperature changes that lag behind a change in an ENSO index by approximately one year. Furthermore, the rates of CO<sub>2</sub> absorption and emission vary with temperature changes during ENSO events, and CO<sub>2</sub> changes lag behind temperature changes by approximately 0.5 - 1 year <xref ref-type="bibr" rid="scirp.136761-8">
     [8]
    </xref>:</p>
   <p>
    <math display="inline" xmlns="http://www.w3.org/1998/Math/MathML"> <mrow> 
      <mi>
        Δ 
      </mi> 
      <mi>
        T 
      </mi> 
      <mo>
        → 
      </mo> 
      <mrow> 
       <mo>
         ( 
       </mo> 
       <mrow> 
        <mn>
          0.5 
        </mn> 
        <mtext>
          - 
        </mtext> 
        <mn>
          1 
        </mn> 
        <mtext>
          year 
        </mtext> 
       </mrow> 
       <mo>
         ) 
       </mo> 
      </mrow> 
      <mo>
        → 
      </mo> 
      <mi>
        Δ 
      </mi> 
      <mi>
        r 
      </mi> 
      <mi>
        c 
      </mi> 
      <msub> 
       <mi>
         o 
       </mi> 
       <mn>
         2 
       </mn> 
      </msub> 
     </mrow> 
    </math> (5)</p>
   <p>CO<sub>2</sub> emissions during El Niño events were interpreted as an increase in plant respiration (decomposition) due to increased temperatures, as reported in previous papers <xref ref-type="bibr" rid="scirp.136761-9">
     [9]
    </xref>-<xref ref-type="bibr" rid="scirp.136761-11">
     [11]
    </xref>. The proposed process for strong El Niño events is shown in <xref ref-type="fig" rid="fig1(a)">
     Figure 1(a)
    </xref> <xref ref-type="bibr" rid="scirp.136761-8">
     [8]
    </xref>.</p>
   <fig id="fig1" position="float">
    <label>Figure 1</label>
    <caption>
     <title>Figure 1. (a) Proposed process for strong El Niño events: an increase in global temperature, an increase in soil respiration, and subsequent global CO<sub>2</sub> emissions <xref ref-type="bibr" rid="scirp.136761-8">
       [8]
      </xref>; (b) the anthropogenic CO<sub>2</sub> emission ratio in the global CO<sub>2</sub> cycles shown in the IPCC report <xref ref-type="bibr" rid="scirp.136761-3">
       [3]
      </xref> <xref ref-type="bibr" rid="scirp.136761-11">
       [11]
      </xref>; and (c) changes in the carbon cycle (ΔCO<sub>2</sub>) due to soil respiration (ΔRs) and global temperature (ΔT) <xref ref-type="bibr" rid="scirp.136761-11">
       [11]
      </xref>.</title>
    </caption>
    <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/4701288-rId23.jpeg?20241023014002" />
   </fig>
   <p>Equations (1)-(5) cast strong doubts that anthropogenic CO<sub>2</sub> is the cause of global warming, although the concept of global warming due to anthropogenic CO<sub>2</sub> has been proposed by the Intergovernmental Panel on Climate Change (IPCC) <xref ref-type="bibr" rid="scirp.136761-12">
     [12]
    </xref>. Anthropogenic CO<sub>2</sub> emissions constitute a small portion of the global CO<sub>2</sub> cycles shown in the IPCC report <xref ref-type="bibr" rid="scirp.136761-3">
     [3]
    </xref> <xref ref-type="bibr" rid="scirp.136761-11">
     [11]
    </xref> (see <xref ref-type="fig" rid="fig1(b)">
     Figure 1(b)
    </xref>):</p>
   <p>
    <math display="inline" xmlns="http://www.w3.org/1998/Math/MathML"> <mtable columnalign="left"> 
      <mtr> 
       <mtd> 
        <mtext>
          anthropogenic 
        </mtext> 
        <mtext>
            
        </mtext> 
        <msub> 
         <mtext>
           CO 
         </mtext> 
         <mtext>
           2 
         </mtext> 
        </msub> 
        <mtext>
            
        </mtext> 
        <mtext>
          ratio 
        </mtext> 
       </mtd> 
      </mtr> 
      <mtr> 
       <mtd> 
        <mo>
          ≒ 
        </mo> 
        <mrow> 
         <mrow> 
          <mrow> 
           <mo>
             ( 
           </mo> 
           <mrow> 
            <mtext>
              fossil 
            </mtext> 
            <mtext>
                
            </mtext> 
            <mtext>
              fuel 
            </mtext> 
            <mtext>
                
            </mtext> 
            <mtext>
              combustion 
            </mtext> 
           </mrow> 
           <mo>
             ) 
           </mo> 
          </mrow> 
         </mrow> 
         <mo>
           / 
         </mo> 
         <mrow> 
          <mrow> 
           <mo>
             ( 
           </mo> 
           <mrow> 
            <mtext>
              fossil 
            </mtext> 
            <mtext>
                
            </mtext> 
            <mtext>
              fuel 
            </mtext> 
            <mtext>
                
            </mtext> 
            <mtext>
              combustion 
            </mtext> 
           </mrow> 
          </mrow> 
         </mrow> 
        </mrow> 
       </mtd> 
      </mtr> 
      <mtr> 
       <mtd> 
        <mtext>
            
        </mtext> 
        <mtext>
            
        </mtext> 
        <mtext>
            
        </mtext> 
        <mtext>
            
        </mtext> 
        <mo>
          + 
        </mo> 
        <mtext>
          respiration 
        </mtext> 
        <mtext>
            
        </mtext> 
        <mtext>
          and 
        </mtext> 
        <mtext>
            
        </mtext> 
        <mtext>
          decomposition 
        </mtext> 
        <mo>
          + 
        </mo> 
        <mrow> 
         <mrow> 
          <mtext>
            ocean 
          </mtext> 
          <mtext>
              
          </mtext> 
          <mtext>
            atmosphere 
          </mtext> 
          <mtext>
              
          </mtext> 
          <mtext>
            exchange 
          </mtext> 
         </mrow> 
         <mo>
           ) 
         </mo> 
        </mrow> 
       </mtd> 
      </mtr> 
      <mtr> 
       <mtd> 
        <mo>
          ≒ 
        </mo> 
        <mrow> 
         <mrow> 
          <mn>
            7.8 
          </mn> 
         </mrow> 
         <mo>
           / 
         </mo> 
         <mrow> 
          <mrow> 
           <mo>
             ( 
           </mo> 
           <mrow> 
            <mn>
              7.8 
            </mn> 
            <mo>
              + 
            </mo> 
            <mn>
              107.2 
            </mn> 
            <mo>
              + 
            </mo> 
            <mn>
              79.2 
            </mn> 
           </mrow> 
           <mo>
             ) 
           </mo> 
          </mrow> 
         </mrow> 
        </mrow> 
        <mtext>
            
        </mtext> 
        <mtext>
            
        </mtext> 
        <mrow> 
         <mo>
           ( 
         </mo> 
         <mrow> 
          <mtext>
            unit 
          </mtext> 
          <mo>
            : 
          </mo> 
          <mtext>
            GtC 
          </mtext> 
         </mrow> 
         <mo>
           ) 
         </mo> 
        </mrow> 
       </mtd> 
      </mtr> 
      <mtr> 
       <mtd> 
        <mo>
          ≒ 
        </mo> 
        <mn>
          0.04 
        </mn> 
       </mtd> 
      </mtr> 
     </mtable> 
    </math> (6)</p>
   <p>As summarized in <xref ref-type="fig" rid="fig1(c)">
     Figure 1(c)
    </xref>, our previous paper <xref ref-type="bibr" rid="scirp.136761-11">
     [11]
    </xref> suggested that temperature changes affect plant decomposition and soil respiration, followed by a change in CO<sub>2</sub> generation. The higher the temperature is, the more CO<sub>2</sub> is generated. On the basis of our results, we concluded that changes in plant decomposition and soil respiration due to global temperatures control global CO<sub>2</sub> cycles. The impact of CO<sub>2</sub> emissions from fossil fuel combustion on global warming is extremely low. In this work, a cross correlation between drco<sub>2</sub>/dt or Δrco<sub>2</sub> and ΔT with a time lag is further clarified.</p>
  </sec><sec id="s2">
   <title>2. Global Data</title>
   <p>Since 1979, the UAH has updated global temperature datasets that represent the piecing together of temperature data from a total of fifteen instruments flying on different satellites over the years. Further details are available <xref ref-type="bibr" rid="scirp.136761-7">
     [7]
    </xref>. Temperatures here were obtained from the datasets, and monthly data and the 13-month average of lower troposphere anomaly values were used.</p>
   <p>The annual mean growth rate of CO<sub>2</sub> in a given year is the difference in concentration between the end of December and the start of January of that year reported by NOAA. Further details are available on their website <xref ref-type="bibr" rid="scirp.136761-6">
     [6]
    </xref>. Because of the seasonal changes in CO<sub>2</sub> concentrations, the annual means and the monthly data are compared.</p>
   <p>These datasets can be downloaded on the websites <xref ref-type="bibr" rid="scirp.136761-6">
     [6]
    </xref> <xref ref-type="bibr" rid="scirp.136761-7">
     [7]
    </xref>, and only two datasets, temperatures and CO<sub>2</sub> concentrations, are analyzed in this paper.</p>
  </sec><sec id="s3">
   <title>3. Results and Discussion</title>
   <p>On the basis of Equation (1), a cross correlation between drco<sub>2</sub>/dt and ΔT with a time lag may be considered, where a correlation coefficient r can be defined as follows (x = drco<sub>2</sub>/dt and y = ΔT):</p>
   <p>
    <xref ref-type="bibr" rid="scirp.136761-"></xref> 
    <math display="inline" xmlns="http://www.w3.org/1998/Math/MathML"> <mrow> 
      <mi>
        r 
      </mi> 
      <mo>
        = 
      </mo> 
      <mfrac> 
       <mrow> 
        <mfrac> 
         <mn>
           1 
         </mn> 
         <mi>
           n 
         </mi> 
        </mfrac> 
        <msubsup> 
         <mstyle mathsize="140%" displaystyle="true"> 
          <mo>
            ∑ 
          </mo> 
         </mstyle> 
         <mrow> 
          <mi>
            i 
          </mi> 
          <mo>
            = 
          </mo> 
          <mn>
            1 
          </mn> 
         </mrow> 
         <mi>
           n 
         </mi> 
        </msubsup> 
        <mrow> 
         <mo>
           ( 
         </mo> 
         <mrow> 
          <mi>
            x 
          </mi> 
          <mi>
            i 
          </mi> 
          <mo>
            − 
          </mo> 
          <mover accent="true"> 
           <mi>
             x 
           </mi> 
           <mo>
             ¯ 
           </mo> 
          </mover> 
          <mo> 
          </mo> 
         </mrow> 
         <mo>
           ) 
         </mo> 
        </mrow> 
        <mrow> 
         <mo>
           ( 
         </mo> 
         <mrow> 
          <mi>
            y 
          </mi> 
          <mi>
            i 
          </mi> 
          <mo>
            − 
          </mo> 
          <mover accent="true"> 
           <mi>
             y 
           </mi> 
           <mo>
             ¯ 
           </mo> 
          </mover> 
         </mrow> 
         <mo>
           ) 
         </mo> 
        </mrow> 
       </mrow> 
       <mrow> 
        <msqrt> 
         <mrow> 
          <mfrac> 
           <mn>
             1 
           </mn> 
           <mi>
             n 
           </mi> 
          </mfrac> 
          <msubsup> 
           <mstyle mathsize="140%" displaystyle="true"> 
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             1 
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             n 
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              ∑ 
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       </mrow> 
      </mfrac> 
     </mrow> 
    </math> (7)</p>
   <p>It has been reported that temperature change and the rate of CO<sub>2</sub> increase are correlated over 40 years, as shown in <xref ref-type="fig" rid="fig2">
     Figure 2
    </xref> from a previous paper <xref ref-type="bibr" rid="scirp.136761-8">
     [8]
    </xref>. Its correlation coefficient r can be calculated via Equation (7). The value of r is 0.73, and the correlation is relatively good, where optionally, the calculation can be easily performed via Excel’s built-in function. Since the 13-month average of temperature change and the annual average of the rate of CO<sub>2</sub> increase are used in <xref ref-type="fig" rid="fig2">
     Figure 2
    </xref>, a time lag within 12 months between drco<sub>2</sub>/dt and ΔT cannot be effectively analyzed.</p>
   <p>In this paper, time lags for selected ENSO events, ①-④, shown in <xref ref-type="fig" rid="fig3">
     Figure 3
    </xref> <xref ref-type="bibr" rid="scirp.136761-8">
     [8]
    </xref>, were analyzed in detail. <xref ref-type="fig" rid="fig4">
     Figure 4
    </xref> shows the changes in CO<sub>2</sub> and temperature anomalies between 2014 and 2018, corresponding to the El Niño ④ events in <xref ref-type="fig" rid="fig3">
     Figure 3
    </xref>. The CO<sub>2</sub> concentration is increasing, but it increases and decreases periodically each year, showing a regular pattern of minimum values in August and maximum values in May each year. Therefore, for each year, we consider the change in CO<sub>2</sub> over the course of a year starting from September as increased CO<sub>2</sub> (ΔCO<sub>2</sub>), as shown in <xref ref-type="fig" rid="fig5">
     Figure 5
    </xref>. Temperatures rise in response to the occurrence of El Niño. CO<sub>2</sub> concentrations also increase in response to temperature increases. This is shown as a larger ΔCO<sub>2</sub> from 2015-2016 in <xref ref-type="fig" rid="fig5">
     Figure 5
    </xref>. Here, we consider the deviation of ΔCO<sub>2</sub> between 2015-2016 and 2014-2015 in <xref ref-type="fig" rid="fig5">
     Figure 5
    </xref>. The deviations in ΔCO<sub>2</sub> and ΔT between 2015-2016 and 2014-2015 are plotted in <xref ref-type="fig" rid="fig6(a)">
     Figure 6(a)
    </xref>. The same data are plotted in <xref ref-type="fig" rid="fig6(b)">
     Figure 6(b)
    </xref>, but ΔT is shifted to the right by five months. The correlation coefficient r is improved from “0.47” to “0.94” by shifting. This means that the CO<sub>2</sub> concentration is determined by temperature changes but with a 5-month time lag. The results prove Equations (4)-(5).</p>
   <fig id="fig2" position="float">
    <label>Figure 2</label>
    <caption>
     <title>Figure 2. Correlations between temperature and CO<sub>2</sub> changes during 1979-2022. Temperature (˚C, red line): 13-month average of lower troposphere anomaly values by UAH with scales on the left. CO<sub>2</sub> (ppm/year, blue vertical lines): difference from the previous year in annual averages by NOAA with scales on the right (a correlation coefficient r = 0.73).</title>
    </caption>
    <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/4701288-rId28.jpeg?20241023014004" />
   </fig>
   <fig id="fig3" position="float">
    <label>Figure 3</label>
    <caption>
     <title>Figure 3. Correlation between temperature and the ENSO index during 1979-2022. Temperature (˚C, red line): 13-month average of lower troposphere anomaly values by UAH with scales on the right. ENSO index (blue vertical lines): two-month average by NOAA with scales on the left <xref ref-type="bibr" rid="scirp.136761-8">
       [8]
      </xref>.</title>
    </caption>
    <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/4701288-rId29.jpeg?20241023014004" />
   </fig>
   <fig id="fig4" position="float">
    <label>Figure 4</label>
    <caption>
     <title>Figure 4. Seasonal change in global CO<sub>2</sub> (blue dots; scale: left axis; unit: ppm) between 2014 and 2018. The red curve shows satellite-based temperatures (scale: right axis, unit: ˚C) during the same period: 13-month average lower troposphere anomaly values by the UAH.</title>
    </caption>
    <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/4701288-rId30.jpeg?20241023014003" />
   </fig>
   <fig id="fig5" position="float">
    <label>Figure 5</label>
    <caption>
     <title>Figure 5. Changes in the annual CO<sub>2</sub> concentration (ppm) from September 2014, 2015, or 2016 to August 2015, 2016, or 2017.</title>
    </caption>
    <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/4701288-rId31.jpeg?20241023014003" />
   </fig>
   <fig id="fig6" position="float">
    <label>Figure 6</label>
    <caption>
     <title>Figure 6. (a) The deviations of ΔCO<sub>2</sub> and ΔT between 2015-2016 and 2014-2015 in Figure 5, and (b) the same data are plotted, but ΔT is shifted to the right by five months. The correlation coefficient r is improved from “0.47” to “0.94” by shifting.</title>
    </caption>
    <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/4701288-rId32.jpeg?20241023014003" />
   </fig>
   <p>Next, other ENSO events, ①-③, were similarly analyzed. Larger deviations in ΔCO<sub>2</sub> were not found for La Niña events ① and ③ but were again found for El Niño events ②, as shown in <xref ref-type="fig" rid="fig7">
     Figure 7
    </xref>. The deviations in ΔCO<sub>2</sub> and ΔT are plotted in <xref ref-type="fig" rid="fig8">
     Figure 8
    </xref>, similar to <xref ref-type="fig" rid="fig6(a)">
     Figure 6(a)
    </xref>. The correlation coefficient r for El Niño ② in <xref ref-type="fig" rid="fig8(b)">
     Figure 8(b)
    </xref> also improved from “0.21” to “0.92” when ΔT was shifted to the right by five months. This means that the CO<sub>2</sub> concentration is determined by temperature changes but with a 5-month time lag. The results also prove equations (4)-(5).</p>
   <fig id="fig7" position="float">
    <label>Figure 7</label>
    <caption>
     <title>Figure 7. Changes in the annual CO<sub>2</sub> concentration (ppm) from September each year during other ENSO periods: (a) La Niña event ① in <xref ref-type="fig" rid="fig3">
       Figure 3
      </xref>, (b) El Niño event ② in <xref ref-type="fig" rid="fig3">
       Figure 3
      </xref>, and (c) La Niña event ③ in <xref ref-type="fig" rid="fig3">
       Figure 3
      </xref>.</title>
    </caption>
    <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/4701288-rId33.jpeg?20241023014003" />
   </fig>
   <fig-group id="fig8" position="float">
    <fig id="fig8" position="float">
     <label>Figure 8</label>
     <caption>
      <title>Figure 8. Deviations in ΔCO2 and ΔT for ①-③ in Figure 7.--Figure 8. Deviations in ΔCO2 and ΔT for ①-③ in Figure 7.</title>
     </caption>
     <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/4701288-rId34.jpeg?20241023014004" />
    </fig>
    <fig id="fig8" position="float">
     <label>Figure 8</label>
     <caption>
      <title>Figure 8. Deviations in ΔCO2 and ΔT for ①-③ in Figure 7.--Figure 8. Deviations in ΔCO2 and ΔT for ①-③ in Figure 7.</title>
     </caption>
     <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/4701288-rId34.jpeg?20241023014004" />
    </fig>
   </fig-group>
   <p>The global CO<sub>2</sub> residence time can be estimated to be 4 years by the IPCC CO<sub>2</sub> cycle budget <xref ref-type="bibr" rid="scirp.136761-3">
     [3]
    </xref> <xref ref-type="bibr" rid="scirp.136761-11">
     [11]
    </xref>, as shown in Equation (8):</p>
   <p>
    <math display="inline" xmlns="http://www.w3.org/1998/Math/MathML"> <mtable columnalign="left"> 
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        </mtext> 
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          time 
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              fossil 
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              fuel 
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        </mtext> 
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        </mtext> 
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    </math> (8)</p>
   <p>The major natural functions affecting ΔCO<sub>2</sub> are (1) plant photosynthesis, (2) CO<sub>2</sub> solubilization into the ocean, and (3) plant decomposition or respiration, as described in the introduction. The periodical annual change in ΔCO<sub>2</sub> is dependent on these functions. Therefore, a time lag for the cross correlation between drco<sub>2</sub>/dt (or ΔCO<sub>2</sub>) and ΔT may be determined by natural functions and the residence time. Although the detailed physical process determining the time lag is not known at this time, our analysis reveals a “5-month” time lag when the temperature leads to a change in CO<sub>2</sub>. It has been considered that temperature and CO<sub>2</sub> simultaneously change or that a change in CO<sub>2</sub> leads to a change in temperature <xref ref-type="bibr" rid="scirp.136761-12">
     [12]
    </xref>. However, a cross-correlation between the global temperature and atmospheric CO<sub>2</sub> with a temperature leading to a “5-month” time lag is noticeable.</p>
   <p>Significant deviations in ΔCO<sub>2</sub> were not found for La Niña events ① and ③, as shown in <xref ref-type="fig" rid="fig7">
     Figure 7
    </xref>. The deviations in ΔCO<sub>2</sub> and ΔT are plotted in <xref ref-type="fig" rid="fig8(a)">
     Figure 8(a)
    </xref> and <xref ref-type="fig" rid="fig8(c)">
     Figure 8(c)
    </xref>, similar to <xref ref-type="fig" rid="fig8(b)">
     Figure 8(b)
    </xref>. A correlation between ΔCO<sub>2</sub> and ΔT is not observed, unlike El Niño ②. A time lag within 12 months between drco<sub>2</sub>/dt and ΔT cannot be effectively analyzed under regular climate periods as shown in <xref ref-type="fig" rid="fig2">
     Figure 2
    </xref>. However, the 5-month time lag was clearly recognized by the analysis during El Niño events, while it was difficult to analyze a time lag during La Niña events.</p>
   <p>Since temperature changes affect plant decomposition and soil respiration (Rs), followed by a change in CO<sub>2</sub> generation, the change rate of soil respiration (dRs/dt) may be expressed as Equation (9), similar to Equation (1) <xref ref-type="bibr" rid="scirp.136761-11">
     [11]
    </xref>:</p>
   <p>
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        </mtext> 
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        </mtext> 
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   <p>Since the average satellite-based global temperature has changed by 0.16˚C/decade <xref ref-type="bibr" rid="scirp.136761-7">
     [7]
    </xref>, soil respiration (Rs) is also expected to increase annually. The temporal increase, dRs/dt, again confirms this proposition, as reported in a previous paper <xref ref-type="bibr" rid="scirp.136761-11">
     [11]
    </xref>. We need more data to calculate a correlation coefficient r between dRs/dt and temperature because the determination of Rs is not straightforward, and only approximate values are available <xref ref-type="bibr" rid="scirp.136761-13">
     [13]
    </xref>-<xref ref-type="bibr" rid="scirp.136761-15">
     [15]
    </xref>.</p>
   <p>If the cross-correlation between global temperature and atmospheric CO<sub>2</sub> with a temperature leading time lag is applied for a current temperature and CO<sub>2</sub> trend, a near-future trend of temperature and CO<sub>2</sub> may be predicted. The El Niño event that started in 2022 is not over at this time (September 2024). The same analysis as that for El Niño ④ events shown in <xref ref-type="fig" rid="fig3">
     Figure 3
    </xref> was conducted for 2022 and 2023 on the basis of the durations of 2021 and 2022. The results are shown in <xref ref-type="fig" rid="fig9">
     Figure 9
    </xref>. The improved correlation coefficient r between ΔCO<sub>2</sub> and ΔT was “0.94” after shifting to 4 months. Although it is a demonstrative example at this time, the estimation of an approximate ΔCO<sub>2</sub> in the near future may be possible.</p>
   <fig id="fig9" position="float">
    <label>Figure 9</label>
    <caption>
     <title>Figure 9. The deviation of ΔCO<sub>2</sub> and ΔT between 2022-2023 and 2021-2022 and ΔT shifted to the right by four months. The correlation coefficient r is improved to “0.97” by shifting.</title>
    </caption>
    <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/4701288-rId39.jpeg?20241023014004" />
   </fig>
  </sec><sec id="s4">
   <title>4. Conclusion</title>
   <p>The temperature change and rate of CO<sub>2</sub> change are correlated but with a time lag, as reported in a previous paper. The correlation was investigated by calculating a correlation coefficient r of these changes for selected ENSO events. Annual periodical increases and decreases in the CO<sub>2</sub> concentration were considered, with a regular pattern of minimum values in August and maximum values in May each year. An increased deviation in CO<sub>2</sub> and temperature was found in response to the occurrence of El Niño, but the increase in CO<sub>2</sub> lagged behind the change in temperature by 5 months. This pattern was not observed for La Niña events. An increase in global CO<sub>2</sub> emissions and a subsequent increase in global temperature proposed by IPCC were not observed, but an increase in global temperature, an increase in soil respiration, and a subsequent increase in global CO<sub>2</sub> emissions were noticed. This natural process can be clearly detected during periods of increasing temperature at El Niño events. The results support Equation (1) or Equation (4) and Equation (5) and cast strong doubts that anthropogenic CO<sub>2</sub> is the cause of global warming.</p>
  </sec><sec id="s5">
   <title>Abbreviations</title>
   <table class="MsoTableGrid custom-table" border="0" cellspacing="0" cellpadding="0"> 
    <tr> 
     <td class="aleft" width="20.95%"><p style="text-align:left">ENSO Index</p></td> 
     <td class="aleft" width="79.05%"><p style="text-align:left">El Niño-Southern Oscillation Index</p></td> 
    </tr> 
    <tr> 
     <td class="aleft" width="20.95%"><p style="text-align:left">IPCC</p></td> 
     <td class="aleft" width="79.05%"><p style="text-align:left">Intergovernmental Panel on Climate Change (the United Nations body)</p></td> 
    </tr> 
    <tr> 
     <td class="aleft" width="20.95%"><p style="text-align:left">NOAA</p></td> 
     <td class="aleft" width="79.05%"><p style="text-align:left">National Oceanic and Atmospheric Administration</p></td> 
    </tr> 
    <tr> 
     <td class="aleft" width="20.95%"><p style="text-align:left">UAH</p></td> 
     <td class="aleft" width="79.05%"><p style="text-align:left">University of Alabama in Huntsville</p></td> 
    </tr> 
    <tr> 
     <td class="aleft" width="20.95%"><p style="text-align:left">drco<sub>2</sub>/dt</p></td> 
     <td class="aleft" width="79.05%"><p style="text-align:left">The change rate of the CO<sub>2</sub> concentration or CO<sub>2</sub> growth rate</p></td> 
    </tr> 
    <tr> 
     <td class="aleft" width="20.95%"><p style="text-align:left">Rs</p></td> 
     <td class="aleft" width="79.05%"><p style="text-align:left">Soil respiration</p></td> 
    </tr> 
    <tr> 
     <td class="aleft" width="20.95%"><p style="text-align:left">ΔT</p></td> 
     <td class="aleft" width="79.05%"><p style="text-align:left">Temperature change</p></td> 
    </tr> 
    <tr> 
     <td class="aleft" width="20.95%"><p style="text-align:left">r</p></td> 
     <td class="aleft" width="79.05%"><p style="text-align:left">correlation coefficient</p></td> 
    </tr> 
   </table>
   <p>
    <xref ref-type="bibr" rid="scirp.136761-"></xref></p>
  </sec>
 </body><back>
  <ref-list>
   <title>References</title>
   <ref id="scirp.136761-ref1">
    <label>1</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Salby, M. (2018) What Is Really Behind the Increase of Atmospheric CO
     <sub>2</sub>? Video Presentation, Helmut-Schmidt-University Hamburg. &gt;https://www.youtube.com/watch?v=rohF6K2avtY 
    </mixed-citation>
   </ref>
   <ref id="scirp.136761-ref2">
    <label>2</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Salby, M. (2016) Atmospheric Carbon. Video Presentation, University College London. &gt;https://www.youtube.com/watch?v=3q-M_uYkpT0 
    </mixed-citation>
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