<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article  PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd"><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article"><front><journal-meta><journal-id journal-id-type="publisher-id">ARS</journal-id><journal-title-group><journal-title>Advances in Remote Sensing</journal-title></journal-title-group><issn pub-type="epub">2169-267X</issn><publisher><publisher-name>Scientific Research Publishing</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.4236/ars.2022.113007</article-id><article-id pub-id-type="publisher-id">ARS-120884</article-id><article-categories><subj-group subj-group-type="heading"><subject>Articles</subject></subj-group><subj-group subj-group-type="Discipline-v2"><subject>Computer Science&amp;Communications</subject></subj-group></article-categories><title-group><article-title>
 
 
  Assessing the Impact of Land Use and Land Cover Change on Air Quality in East Baton Rouge—Louisiana Using Earth Observation Techniques
 
</article-title></title-group><contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Diana</surname><given-names>B. Frimpong</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Yaw</surname><given-names>A. Twumasi</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Zhu</surname><given-names>H. Ning</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Abena</surname><given-names>B. Asare-Ansah</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Matilda</surname><given-names>Anokye</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Priscilla</surname><given-names>M. Loh</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Faustina</surname><given-names>Owusu</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Caroline</surname><given-names>Y. Apraku</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Recheal</surname><given-names>N. D. Armah</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Judith</surname><given-names>Oppong</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>John</surname><given-names>B. Namwamba</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib></contrib-group><aff id="aff1"><addr-line>Department of Urban Forestry and Natural Resources, Southern University and A &amp;amp; M College, 102 Fisher Hall, Baton Rouge, Louisiana, USA</addr-line></aff><pub-date pub-type="epub"><day>30</day><month>09</month><year>2022</year></pub-date><volume>11</volume><issue>03</issue><fpage>106</fpage><lpage>119</lpage><history><date date-type="received"><day>13,</day>	<month>May</month>	<year>2022</year></date><date date-type="rev-recd"><day>27,</day>	<month>September</month>	<year>2022</year>	</date><date date-type="accepted"><day>30,</day>	<month>September</month>	<year>2022</year></date></history><permissions><copyright-statement>&#169; Copyright  2014 by authors and Scientific Research Publishing Inc. </copyright-statement><copyright-year>2014</copyright-year><license><license-p>This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/</license-p></license></permissions><abstract><p>
 
 
  There has been significant research in recent decades on Land use Land cover (LULC) changes and their influence on biodiversity but little to no research on its impact on air quality. This research seeks to demonstrate how geospatial technologies such as geographic information system (GIS) and remote sensing can be used to assess the effects of LULC changes on particulate matter emissions and their impact on air quality in the East Baton Rouge area. In pursuit of these objectives, this study uses LANDSAT imageries from the past 30 years specifically Landsat Thematic Mapper (TM C2L2) and Landsat 8 Operational Land Imager/Thermal Infrared (OLI/TIRS C2L2) covering 1991, 2001, 2011 and 2021 were collected, processed, and analyzed for the LULC change analysis using QGIS software. Additionally, Sentinel 5P and the Air quality index from the U.S. Environmental Protection Agency (EPA) were used to assess the air quality trend over the years to establish the correlation between LULC and air quality. Results showed an increasing trend in air quality over the past 3 decades with concentrations of CO, NO
  <sub>2</sub>, and PM2.5 abruptly falling however, urbanization and the population expanded throughout the time. The paper concludes by outlining a policy recommendation in the form of encouraging Louisiana residents to use alternative renewable energies rather than the over-dependence on coal-fired electric generating plants that have an impact on the environment.
 
</p></abstract><kwd-group><kwd>Google Earth Engine</kwd><kwd> Aerosol</kwd><kwd> Air Quality</kwd><kwd> Sentinel-5P</kwd><kwd> Land Use Land Cover Change</kwd></kwd-group></article-meta></front><body><sec id="s1"><title>1. Introduction</title><p>Poor quality of air is among the most serious environmental concerns in many cities throughout the world. Given that cities are home to more than half of the world’s population, the impact of air pollution on human health must be addressed. Air pollution, a significant contributor to climate change, has been debated in most developed countries and local governments have made improving air quality a priority for health. Consumption of energy, emissions from industries, and automobile traffic all rise when cities expand in size and population, both of which can negatively impact the quality of air [<xref ref-type="bibr" rid="scirp.120884-ref1">1</xref>]. Emissions have increased by about 15% in every half-million growth in the human population and particulates are among the most well-known and controlled air contaminants (PM) [<xref ref-type="bibr" rid="scirp.120884-ref2">2</xref>].</p><p>Particulate Matter (PM) is a combination of both solid and liquid particles present in the air [<xref ref-type="bibr" rid="scirp.120884-ref3">3</xref>]. Dust, smog, soot, smoke, and soil are examples. Such particulates can originate from anthropogenic activities like biomass burning, fossil fuel combustion or radioactive isotopes like dust and sea salt. Also, various forms of Land Use Land Cover (LULC) activities prevalent in the major urban centers can affect the quantity of PM [<xref ref-type="bibr" rid="scirp.120884-ref4">4</xref>]. Consumption of energy, emissions from industries, and automobile traffic all rise when cities expand in size and population, both of which can negatively impact the quality of air [<xref ref-type="bibr" rid="scirp.120884-ref5">5</xref>]. PM is also caused by the generation of particles from released gases, including Nitroxide (NO<sub>2</sub>), Volatile Organic Compound (VOC), and ammonia [<xref ref-type="bibr" rid="scirp.120884-ref5">5</xref>].</p><p>There are various forms of PM. PM2.5 refers to particles with a smooth diameter of not more than 2.5 m, which are tiny enough to be breathed. Numerous studies have linked extreme pollution episodes to a higher incidence of disease and fatalities over the last century [<xref ref-type="bibr" rid="scirp.120884-ref5">5</xref>]. In the past few decades, attention has switched to the effect of the extended contact with PM in the medium levels, as observed in populated areas. According to [<xref ref-type="bibr" rid="scirp.120884-ref6">6</xref>], frequent reference to PM2.5 has also been associated with a higher cardiovascular risk, respiratory disorders, and lung cancer. PM2.5 leads to various short-term health problems, including respiratory illnesses, nose, eye irritation, and headaches [<xref ref-type="bibr" rid="scirp.120884-ref6">6</xref>]. Individual particles limit visibility and constitute hazardous substances that can damage the environment through wet or dry deposition regarding health risks [<xref ref-type="bibr" rid="scirp.120884-ref4">4</xref>].</p><p>The form of PM and its intensity vary by region, but mostly around more developed urban centers, there is more variation. By substituting native vegetation cover with artificial pollution sources, the forms of LULC activities prevalent in the major urban centers can affect the quantity of PM [<xref ref-type="bibr" rid="scirp.120884-ref4">4</xref>]. The transformation of woodland, grasslands, and farms into industrial complexes, residential development, and vast commercial areas frequently results in increased pollution. Urban sprawl has been the most extreme example of this sort of growth, defined by dispersed structures of low-density expansion, frequently in an electric car manner [<xref ref-type="bibr" rid="scirp.120884-ref7">7</xref>]. There have always been several primary causes of air pollution, but there are also secondary causes of pollution by particles that occur from chemical interactions in the lower stratosphere. PM is also caused by the generation of particles from released gases, including NO<sub>2</sub> and VOC, and ammonia [<xref ref-type="bibr" rid="scirp.120884-ref5">5</xref>]. Furthermore, air pollution can be carried from one place to another, making the matter much more complicated.</p><p>In remote areas where there is no ground-based instrumentation, global satellite observations enable the early identification and tracking of various atmospheric gases released by natural occurrences and human action [<xref ref-type="bibr" rid="scirp.120884-ref8">8</xref>]. This indicates that the rapid evolution of technology and the ever-advancing techniques of geospatial science these days have presented innovative solutions and appropriate tools through G.I.S applications for researchers and concerned institutions to contribute to better management of the environment. One of such ways is the study of land use and land cover change detection. Land cover changes are the various feature changes that occur on land for instance a change in vegetation patterns, and soil conditions amongst others, whereas land-use change is the change in the utilization of land. According to [<xref ref-type="bibr" rid="scirp.120884-ref9">9</xref>], worsening environmental air quality, loss of agricultural lands, destruction of wetlands, and loss of biodiversity and animal habitat have all become issues that need knowledge of land use/land cover. Therefore, studying land use/land cover (LU/LC) changes is critical for appropriate planning, usage, and management of natural resources [<xref ref-type="bibr" rid="scirp.120884-ref10">10</xref>]. In effect, LULC change studies and their influence on biodiversity and climate have been a subject of significant research in recent decades [<xref ref-type="bibr" rid="scirp.120884-ref11">11</xref>] [<xref ref-type="bibr" rid="scirp.120884-ref12">12</xref>] [<xref ref-type="bibr" rid="scirp.120884-ref13">13</xref>] [<xref ref-type="bibr" rid="scirp.120884-ref14">14</xref>] [<xref ref-type="bibr" rid="scirp.120884-ref15">15</xref>] but none on its impacts on air quality. Current scholarly work in Louisiana bothers on the use of various technologies to study changes in land areas and urban forest cover, distribution of toxic sites, various time series analysis on rainfall stations which carry equal importance, but all fail to take a dive on how the changes in land use and land cover affect air quality in the region over the years [<xref ref-type="bibr" rid="scirp.120884-ref16">16</xref>] [<xref ref-type="bibr" rid="scirp.120884-ref17">17</xref>] [<xref ref-type="bibr" rid="scirp.120884-ref18">18</xref>] [<xref ref-type="bibr" rid="scirp.120884-ref19">19</xref>] [<xref ref-type="bibr" rid="scirp.120884-ref20">20</xref>]. Therefore, the overall objective of this study is to demonstrate how geospatial technologies such as GIS and remote sensing can be used to assess the impact of LULC changes on particulate matter emissions and the emission of other harmful gases such as nitroxide and carbon monoxide, and their impact on air quality in the East Baton Rouge area. Specifically, this study will assess land use and land cover changes of the East Baton Rouge Parish from 1991 to 2021, using earth observation techniques; analyze the trend of air quality over the years specifically NO<sub>2</sub>, CO, and PM2.5 using sentinel 5P imageries and air quality monitoring station data from the Environmental Protection Agency (EPA).</p></sec><sec id="s2"><title>2. Methodology</title><sec id="s2_1"><title>2.1. The Study Area</title><p>East Baton Rouge is one of the parishes in Louisiana and it hosts the state’s capital Baton Rouge (<xref ref-type="fig" rid="fig1">Figure 1</xref>). According to [<xref ref-type="bibr" rid="scirp.120884-ref21">21</xref>], the parish has an estimated population of 453,301 people in 2021, with 220,553 people living in Baton Rouge city. The climate is humid subtropical, with hot and humid summers, warm winters, and medium to heavy rains regularly. Baton Rouge’s yearly estimated temperature is 67.5 degrees Fahrenheit, with an estimated temperature of 51.7 degrees Fahrenheit in January and an average temperature of 81.9 degrees Fahrenheit in August [<xref ref-type="bibr" rid="scirp.120884-ref22">22</xref>]. The mean annual precipitation in this area is 57.9 rain inches and 0.1 snow inches. In 2000, East Baton Rouge compared to its adjacent parishes like Livingston and Ascension was perhaps the most industrialized parish in the area, with about 18% of its territory classified as developed, compared to around 5% for the rest of the parishes [<xref ref-type="bibr" rid="scirp.120884-ref23">23</xref>]. Also, the East Baton Rouge region has seen substantial development in the previous half of the century, notably in its outskirts. Between 2000 and 2020, the town expanded by 174.2 miles, placing it 27th in the US city expansion [<xref ref-type="bibr" rid="scirp.120884-ref24">24</xref>]. The region is known for hosting a state college, two major universities, several prominent hospitals, and six medical research centers. East Baton Rouge is a significant manufacturing, medical, petrochemical, and scientific hub in the southern United States. The refinery company, ExxonMobil, the country’s third-largest oil plant, is located in this parish (<xref ref-type="fig" rid="fig1">Figure 1</xref>). Because of its record of steel manufacturing and position as a heartland of industrial activities in the Southeast, East Baton Rouge has a lengthy history of air pollution issues.</p><p>In 2000, severe air pollution episodes prompted a few of the Federal Clean Air Act [<xref ref-type="bibr" rid="scirp.120884-ref4">4</xref>]. Whereas overall air quality is better from then, the Baton Rouge Metropolitan Statistical Area (MSA) remains in the top ten for worst particulate contamination. East Baton Rouge and its adjacent parishes, Livingston, and Ascension have consistently failed to meet the EPA quality of air guidelines. American Lung Association [<xref ref-type="bibr" rid="scirp.120884-ref25">25</xref>] ranked Baton Rouge as the 57th most polluted</p><p>and ranked 38th most polluted for ozone nationally. Three substantial coal-fired power stations run in those states which can be to blame for this. The expanding population of the region has prompted the construction of these power facilities and their development in the past few years. The parish has a complete PM tracking system due to its prior difficulties with the pollution of air. This, combined with its rapid expansion, makes it an obvious candidate for a first situation analysis.</p></sec><sec id="s2_2"><title>2.2. Data Acquisition</title><p>This study used two types of data. Remote sensing data and Air Quality Index Summary data from the Environmental Protection Agency (EPA). Landsat level 2 images were acquired from the United States Geological Survey (USGS) earth explorer website and were used to study the changes within the landscape over the last three (3) decades [<xref ref-type="bibr" rid="scirp.120884-ref26">26</xref>]. Specifically, Landsat 5 Thematic Mapper (TM C2L2) satellite images for 1991 (date: 10/10/1991), 2001 (date: 05/14/2001), 2011 (date: 10/01/2011), and Landsat 8 Operational Land Imager/Thermal Infrared (OLI/TIRS C2L2) for the 2021 satellite image (date: 09/26/2021). The images were selected based on the availability of cloud-free images for the area of interest. This Landsat collection derived from the Level 2 product was atmospherically corrected and hence required no preprocessing [<xref ref-type="bibr" rid="scirp.120884-ref27">27</xref>]. It was loaded into QGIS and clipped using the study area boundary for further analysis.</p></sec><sec id="s2_3"><title>2.3. Air Quality Analysis</title><p>For the air quality analysis, we extracted time-series information on carbon monoxide (CO), and nitrogen dioxide (NO<sub>2</sub>) concentrations from the Sentinel-5P archives available on Google Earth Engine. This cloud-based free platform launched by Google in 2010 can host petabytes of satellite images and other geospatial datasets useful for mapping trends and detecting changes in the landscape [<xref ref-type="bibr" rid="scirp.120884-ref28">28</xref>]. The Sentinel-5P product launched by the European Space Agency (ESA) in 2017 has a spatial resolution of 1113.2 meters and daily global coverage. We focused on datasets for October 2018, 2020, and March 2022 to monitor the changes in these greenhouse gas concentrations over time. After applying the temporal and spatial filters in the GEE code, the NO<sub>2</sub> and CO products were generated for the study area. This was then exported into ArcMapfor map composition.</p><p>Due to the lack of historical data associated with the Sentinel 5p satellite imageries, air quality (AQ) station data summarized in the Air Quality Index for the East Baton Rouge Report available on the EPA website was generated to analyze the air quality trends 30 years ago. This report considers all the criteria for air pollutants detected within a geographic region, hence making the Index a good indicator of overall air quality in a region. It specifically provides air quality standards-related summary data for carbon mono oxide, nitrox dioxide, ozone, sulfur dioxide, PM2.5 and 10, and lead by city or county.</p></sec><sec id="s2_4"><title>2.4. Image Processing</title><p>In QGIS, the Semi-Automatic Classification Plugin (SCP) was used to analyze the data. Specifically, the supervised classification method was employed using the Random Forest classifier. This algorithm is made up of individual decision trees that work as an ensemble. Each tree in the random forest algorithm outputs a prediction based on the class and the class with the highest votes becomes the prediction of the model. By increasing the number of decision trees, the accuracy of the model is also increased [<xref ref-type="bibr" rid="scirp.120884-ref29">29</xref>]. This method can produce a highly accurate classification compared with other commonly used methods [<xref ref-type="bibr" rid="scirp.120884-ref30">30</xref>] [<xref ref-type="bibr" rid="scirp.120884-ref31">31</xref>]. The Random Forest classifier categorized the land cover into four different classes: water, vegetation, bare land, and urban areas for the selected years. The parameters required for the model included the band set, class ID, number of training samples, and number of decision trees. For this study, we used 5000 training samples and 100 decision trees to run the random forest model for each year.</p></sec></sec><sec id="s3"><title>3. Results and Discussion</title><sec id="s3_1"><title>3.1. Land Use Land Cover Analysis</title><p>As shown in the produced map (<xref ref-type="fig" rid="fig2">Figure 2</xref>), East Baton Rouge parish has sustained its pattern of expansion and land cover change since 1991. It was seen</p><p>that vegetation was the most dominated LULC class for all years from 1991, 2001, 2011 and 2021. However, over time, the growth of urban areas increased exponentially. <xref ref-type="table" rid="table1">Table 1</xref> gives the statistical results of LULC changes. Over the years, Urban areas in the East Baton Rouge parish increased exponentially from 10.48% in 1991 to 24.92% in 2021 due to urban expansion and population increase. The study area witnessed a large amount of agricultural land converted into settlements and other urban development activities. Vegetation and agricultural lands decreased from 79.93% (1991) to 67.81% (2021). Water spread area also increased from 2.13% in 1991 to 2.64% in 2021, Bare land decreased from 7.66% (1991) to 4.63% (2021) with a net decrease of 3.03% due to the gradual conversion of bare areas into built-up areas or human developmental areas as the population increased significantly during the past decades. This establishes changes in land use patterns in East Baton Rouge over the years and the gradual occurrence of urbanization.</p></sec><sec id="s3_2"><title>3.2. Classification Accuracy Assessment</title><p>Overall LULC classification accuracy levels ranged from 92 to 97 percent for the four days the different satellite imageries were collected, with Kappa indices of agreement spanning from 90 to 95 percent (<xref ref-type="table" rid="table2">Table 2</xref>). This makes it acceptable for the research because it meets the Anderson categorization scheme’s minimal accuracy requirement of 85% [<xref ref-type="bibr" rid="scirp.120884-ref32">32</xref>].</p><table-wrap id="table1" ><label><xref ref-type="table" rid="table1">Table 1</xref></label><caption><title> LULC classes for the period 1991 to 2021 in percentages</title></caption><table><tbody><thead><tr><th align="center" valign="middle"  rowspan="2"  >Land Use</th><th align="center" valign="middle"  colspan="4"  >Percentage (%)</th></tr></thead><tr><td align="center" valign="middle" >1991</td><td align="center" valign="middle" >2001</td><td align="center" valign="middle" >2011</td><td align="center" valign="middle" >2021</td></tr><tr><td align="center" valign="middle" >Water bodies</td><td align="center" valign="middle" >2.13</td><td align="center" valign="middle" >2.50</td><td align="center" valign="middle" >2.38</td><td align="center" valign="middle" >2.64</td></tr><tr><td align="center" valign="middle" >Vegetation</td><td align="center" valign="middle" >79.73</td><td align="center" valign="middle" >55.65</td><td align="center" valign="middle" >73.30</td><td align="center" valign="middle" >67.81</td></tr><tr><td align="center" valign="middle" >Bare land</td><td align="center" valign="middle" >7.66</td><td align="center" valign="middle" >27.09</td><td align="center" valign="middle" >4.37</td><td align="center" valign="middle" >4.63</td></tr><tr><td align="center" valign="middle" >Urban Area</td><td align="center" valign="middle" >10.48</td><td align="center" valign="middle" >14.75</td><td align="center" valign="middle" >19.95</td><td align="center" valign="middle" >24.92</td></tr></tbody></table></table-wrap><table-wrap id="table2" ><label><xref ref-type="table" rid="table2">Table 2</xref></label><caption><title> Shows the accuracy assessment (in percent) of the LULC maps for the various years (1991, 2001, 2011 and 2021)</title></caption><table><tbody><thead><tr><th align="center" valign="middle"  rowspan="2"  >LULC Classes</th><th align="center" valign="middle"  colspan="2"  >1991</th><th align="center" valign="middle"  colspan="2"  >2001</th><th align="center" valign="middle"  colspan="2"  >2011</th><th align="center" valign="middle"  colspan="2"  >2021</th></tr></thead><tr><td align="center" valign="middle" >User Accuracy (%)</td><td align="center" valign="middle" >Producer Accuracy (%)</td><td align="center" valign="middle" >User Accuracy (%)</td><td align="center" valign="middle" >Producer Accuracy (%)</td><td align="center" valign="middle" >User Accuracy (%)</td><td align="center" valign="middle" >Producer Accuracy (%)</td><td align="center" valign="middle" >User Accuracy (%)</td><td align="center" valign="middle" >Producer Accuracy (%)</td></tr><tr><td align="center" valign="middle" >Water</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >86</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >100</td></tr><tr><td align="center" valign="middle" >Vegetation</td><td align="center" valign="middle" >93</td><td align="center" valign="middle" >93</td><td align="center" valign="middle" >92</td><td align="center" valign="middle" >95</td><td align="center" valign="middle" >98</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >97</td><td align="center" valign="middle" >100</td></tr><tr><td align="center" valign="middle" >Bare land</td><td align="center" valign="middle" >87</td><td align="center" valign="middle" >86</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >88</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >85</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >94</td></tr><tr><td align="center" valign="middle" >Urban Areas</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >98</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >92</td><td align="center" valign="middle" >92</td></tr><tr><td align="center" valign="middle" >Overall accuracy</td><td align="center" valign="middle"  colspan="2"  >94</td><td align="center" valign="middle"  colspan="2"  >92</td><td align="center" valign="middle"  colspan="2"  >94</td><td align="center" valign="middle"  colspan="2"  >97</td></tr><tr><td align="center" valign="middle" >Kappa statistic</td><td align="center" valign="middle"  colspan="2"  >91</td><td align="center" valign="middle"  colspan="2"  >90</td><td align="center" valign="middle"  colspan="2"  >91</td><td align="center" valign="middle"  colspan="2"  >95</td></tr></tbody></table></table-wrap></sec><sec id="s3_3"><title>3.3. Air Quality Trend Analysis</title><p>TROPOMI on the Sentinel 5 Precursor (S5P) satellite is designed to measure CO, NO<sub>2</sub>, and other various atmospheric constituent abundance using clear-sky and cloudy-sky earth radiance observations in the 2.3 &#181;m spectral area of the shortwave infrared (SWIR) sector of the solar spectrum. Out of that, we created a modest map (<xref ref-type="fig" rid="fig3">Figure 3</xref>) that shows the NO<sub>2</sub> spatial concentration from 2018 to 2022. The pixels in red and blue indicate areas where NO<sub>2</sub> concentrations are relatively higher or lower, respectively. This could be related to the prevailing land use pattern from east to the north over East Baton Rouge.</p><p>For carbon monoxide concentration in 2018, there was a high concentration of CO in the Northern parts of East Baton Rouge but a slight decrease in the south. However, 2020 saw a drastic decline in carbon monoxide concentration in almost every part of East Baton Rouge according to <xref ref-type="fig" rid="fig4">Figure 4</xref> and this could be a result of the effect of the outbreak of COVID 19. The burning of fossil fuels, biomass, and the oxidation of methane and other hydrocarbons in the atmosphere are the primary sources of CO therefore the reduction in the production of these fuels as a result of a decline in demand and restriction of movement during the pandemic had a ripple effect on carbon monoxide concentration and this is evident in the map. Comparatively, 2022 experienced a somewhat increase in CO concentrations in most areas of East Baton Rouge (<xref ref-type="fig" rid="fig4">Figure 4</xref>) and this could also be attributed to our return to normalcy after the pandemic. The pixels in red and green indicate areas where the CO levels are relatively higher or lower, respectively.</p><p>The Sentinel 5 Precursor (S5P) satellite was operational in 2017, hence lacking historical data. To supplement the loss, this study analyzed the EPA’s Summarized Air Quality Index for air quality trend analysis from 1991 to 2021. The air quality index is a daily air quality indicator that is used to report on the condition of the air we breathe. It indicates whether the air is clean or polluted, as well as any potential health risks that could be associated with the polluted air. It also provides yearly summaries of a city’s or county’s air pollution levels. The report displays the highest readings reported by all county monitors during the year and highlights text to identify values that exceed an air quality threshold as shown in <xref ref-type="table" rid="table3">Table 3</xref>.</p><p>Focusing on PM2.5, PM 10, NO<sub>2</sub>, and CO trends over the years (<xref ref-type="fig" rid="fig5">Figure 5</xref>), the data collected for this investigation revealed situations where the concentration of these pollutants abruptly fell showing an increase in air quality in 2021 and this is represented in <xref ref-type="fig" rid="fig5">Figure 5</xref> below. When we compare NO<sub>2</sub> and CO emissions for East Baton Rouge in 1991 with those for the year 2021, we find a drop of roughly from 19 and 7 ppm to 7 and 1.4 ppm respectively in 2021. Regarding PM2.5 and PM10, the same comparison indicates a reduction of approximately 60%, from 0 and 28 ppm annual mean in 1991 to 8.5 and 16 ppm in 2021. Considering that these decreases happened throughout rapid solid industrialization</p><table-wrap id="table3" ><label><xref ref-type="table" rid="table3">Table 3</xref></label><caption><title> Shows the air quality index summary for east baton rouge between 1991, 2001, 2011 and 2021. CO 1-hr 2nd Max stands for Carbon Monoxide with the year’s second-highest 1-hour measurement. NO<sub>2</sub> Annual Mean is the annual mean of all 1-hour measurements taken throughout the year whereas the PM2.5 wtd and PM10 Annual mean is the Weighted Annual mean for the calendar year. Statistics in red represent data readings above the respective air quality standard level</title></caption><table><tbody><thead><tr><th align="center" valign="middle" >County</th><th align="center" valign="middle" >CO 1-hr 2nd Max</th><th align="center" valign="middle" >CO 8-hr 2nd Max</th><th align="center" valign="middle" >NO<sub>2</sub> 98th %ile</th><th align="center" valign="middle" >NO<sub>2</sub> Annual Mean</th><th align="center" valign="middle" >O<sub>3</sub> 1-hr 2nd Max</th><th align="center" valign="middle" >O<sub>3</sub> 8-hr 4th Max</th><th align="center" valign="middle" >PM2.5 98th %ile</th><th align="center" valign="middle" >PM2.5 Wtd. Mean</th><th align="center" valign="middle" >PM10 24-hr 2nd Max</th><th align="center" valign="middle" >PM10 Annual Mean</th></tr></thead><tr><td align="center" valign="middle" >East Baton Rouge, (1991)</td><td align="center" valign="middle" >7</td><td align="center" valign="middle" >4.8</td><td align="center" valign="middle" >77</td><td align="center" valign="middle" >19</td><td align="center" valign="middle" >0.14</td><td align="center" valign="middle" >0.097</td><td align="center" valign="middle" >.</td><td align="center" valign="middle" >.</td><td align="center" valign="middle" >54</td><td align="center" valign="middle" >28</td></tr><tr><td align="center" valign="middle" >East Baton Rouge, (2001)</td><td align="center" valign="middle" >6.5</td><td align="center" valign="middle" >4.8</td><td align="center" valign="middle" >64</td><td align="center" valign="middle" >17</td><td align="center" valign="middle" >0.11</td><td align="center" valign="middle" >0.082</td><td align="center" valign="middle" >32</td><td align="center" valign="middle" >14.2</td><td align="center" valign="middle" >52</td><td align="center" valign="middle" >26</td></tr><tr><td align="center" valign="middle" >East Baton Rouge, (2011)</td><td align="center" valign="middle" >1.7</td><td align="center" valign="middle" >1.4</td><td align="center" valign="middle" >56</td><td align="center" valign="middle" >12</td><td align="center" valign="middle" >0.12</td><td align="center" valign="middle" >0.083</td><td align="center" valign="middle" >26</td><td align="center" valign="middle" >12.5</td><td align="center" valign="middle" >73</td><td align="center" valign="middle" >33</td></tr><tr><td align="center" valign="middle" >East Baton Rouge, (2021)</td><td align="center" valign="middle" >1.4</td><td align="center" valign="middle" >0.9</td><td align="center" valign="middle" >37</td><td align="center" valign="middle" >7</td><td align="center" valign="middle" >0.09</td><td align="center" valign="middle" >0.063</td><td align="center" valign="middle" >19</td><td align="center" valign="middle" >8.5</td><td align="center" valign="middle" >46</td><td align="center" valign="middle" >16</td></tr></tbody></table></table-wrap><p>in the area with three substantial coal-fired power stations running in the state (<xref ref-type="fig" rid="fig6">Figure 6</xref>), makes it even more astonishing. This clearly shows that these decreases over the span of thirty years cannot be accounted for just by land use, and several reasons could have contributed to this pattern. These reductions are most likely due to the state’s adherence to US EPA guidelines rather than it being directly tied to development. These factors could disguise the actual influence of modernization on air quality in an area after analyzing the air quality pattern in the previous years and relating it to the rising quantity and population of city land construction. A study by [<xref ref-type="bibr" rid="scirp.120884-ref33">33</xref>] confirmed the concentration of PM2.5 declined dramatically with the establishment of PM2.5 limits in 2001 and their amendment in 2016 and this study affirms it.</p></sec></sec><sec id="s4"><title>4. Conclusions</title><p>The rapid evolution of technology and the ever-advancing techniques of Geospatial science presented innovative solutions and appropriate tools through G.I.S applications for researchers and concerned institutions to contribute to better management of the environment. Satellite imageries can be valuable in evaluating pollutant emissions in regions where surface sensors are non-existent or limited. As a result, we have a full view of individual concentrations of air pollutants, which allows us to analyze well LULC changes to air quality across a greater area, which will be hard to do with just surface data.</p><p>However, considering exterior impacts on every variable, establishing a relationship with changes in LULC and PM2.5 is a difficult task. Using East Baton Rouge and the southern Louisiana region as a case study, this research aimed at demonstrating how geospatial technologies such as GIS and remote sensing can be used to assess the effects of land use and land cover changes on particulate matter emissions and their impact on air quality. The data collected for this investigation revealed an increasing trend in air quality over the past 3 decades with a concentration of CO, NO<sub>2</sub>, and PM2.5 abruptly falling however, urbanization and the population expanded throughout this time. This could be attributed to several external factors like the region’s adherence to EPA Air quality regulations which is likely to muddle the association between the number and form of modification in LULC and the PM. This study has proven that the East Baton Rouge region has made significant progress in terms of air quality, and this should encourage policymakers on the effectiveness of federal and state regulations such as the Federal Clean Air Act. In the future, Louisiana residents can be encouraged on the use of alternative renewable energies rather than the over-dependence on coal-fired electric generating plants that have an impact on the environment.</p></sec><sec id="s5"><title>Acknowledgements</title><p>The authors would like to acknowledge the USDA National Institute of Food and Agriculture (NIFA) McIntire Stennis Forestry Research Program funded project with award number NI22MSCFRXXXG077. Also, we would like to extend our sincere gratitude to the Dean of Graduate Studies at Southern University in Baton Rouge, Louisiana, Professor Ashagre Yigletu, for providing graduate assistantships to some of the graduate students on this paper in order to promote research and help the students acquire the necessary skill development while earning a graduate degree.</p></sec><sec id="s6"><title>Conflicts of Interest</title><p>The authors declare no conflicts of interest regarding the publication of this paper.</p></sec><sec id="s7"><title>Cite this paper</title><p>Frimpong, D.B., Twumasi, Y.A., Ning, Z.H., Asare-Ansah, A.B., Anokye, M., Loh, P.M., Owusu, F., Apraku, C.Y., Armah, R.N.D., Oppong, J. and Namwamba, J.B. (2022) Assessing the Impact of Land Use and Land Cover Change on Air Quality in East Baton Rouge—Louisiana Using Earth Observation Techniques. 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