Electrical Conductivity of Spark Plasma Sintered W-Cu and Mo-Cu Composites for Electrical Contact Applications

Tungsten copper and molybdenum copper composites, with weight percent copper in the range of 20% - 40%, have been produced using the spark plasma sintering (SPS) technique. Other specimens having similar compositions were also developed using the conventional techniques of Liquid Phase Sintering (LPS) and Infiltration. Electrical conductivity measurements showed that the specimens produced by the SPS process had substantially higher levels of electrical conductivity than those produced by the other methods. Relative density measurements showed that the SPS specimens achieved very high densification, with relative densities in the range of 99.1% - 100%. On the other hand, the specimens produced by LPS and infiltration had relative densities in the range of 88% - 92% and 96% - 98% respectively. The superior conductivity of the SPS specimens has been attributed to the virtually full densification achieved by the process. The effect of porosity on electrical conductivity has been discussed and three standard models were assessed using results from porous sintered skeletons of pure tungsten and pure molybdenum.

• Sintering
• Infiltration
• Conductivity
• Porosity
• Spark Plasma
• Electrical Contact
• Relative Density

1. Introduction

Electrical contacts are generally made from metals of high electrical conductivity such as alloys of silver, copper, gold, platinum and palladium. These types of contact materials are commonly produced by liquid metallurgy processing techniques. The basic properties required from such contact materials are good electrical conductivity, corrosion resistance, hardness, and fairly good resistance to mechanical wear. For some industrial applications, however, such as high-power equipment brushes, there is a need for a substantially high hardness and high resistance to abrasive wear. Refractory based electrical contacts are required for such applications.

Refractory metals such as tungsten and molybdenum have limited current carrying capacity due to their relatively low electrical conductivity and high contact resistance even with high contact forces. However, because of their high melting points and boiling points, they offer very high resistance to mechanical wear, electrical arc erosion and welding, and are therefore very good electrical contact materials where these special properties are required. Their electrical conductivity can be enhanced by developing them in the form of composites with metals such as copper and silver. The aim here is to combine the high melting point and arc erosion resistance of W or Mo with the low melting point and high electrical conductivity of copper (Cu).

Composite materials such as W-Cu, Mo-Cu, W-Ag and Mo-Ag are generally produced using techniques such as Powder Metallurgy (PM), Powder Injection Moulding (PIM), Metal Injection Moulding (MIM), High Energy Ball Milling (or Mechanical Alloying), and other related techniques which exclude the basic solidification processing techniques of melting and casting because of the high melting points of the refractory metals tungsten (3410˚C) and molybdenum (2610˚C). Details of such related techniques are available in the literature [1] [2] [3] [4] [5].

The two main powder metallurgy processes employed for the commercial production of the composites are Infiltration and Liquid Phase Sintering (LPS). In the LPS process, the tungsten (or molybdenum) powder is thoroughly blended with the copper powder and the blend is compacted and then sintered in a furnace at a temperature higher than the melting point of copper. Thus the copper melts and flows to fill the voids between the particles of tungsten (or molybdenum), after which the composite is cooled down to room temperature. In the Infiltration process, on the other hand, the pure tungsten (or molybdenum) powder is compacted and sintered in a furnace at a suitable temperature to obtain porous sintered skeletons of pure W (or Mo). Subsequently an appropriate amount of copper is placed on top of the sintered skeletons and heated in a furnace. The copper melts and is drawn by capillary forces to fill the pores in the pre-sintered skeletons. Although the infiltration process is a less cost-efficient process than the LPS process, and is a laborious, time-consuming two-stage thermal cycle process, it has a broad practical range of applications and is the preferred process in the electrical contact manufacturing industry. The composites produced by both the infiltration and LPS processes are generally within the 10 - 40 wt% Cu range [6].

The Spark Plasma Sintering (SPS) process, otherwise called the Pulsed Electric Current Sintering (PECS) process is a much more recent process that is not yet commercially available on a large scale. The mechanism of the method is based on the micro-spark discharge in the gap between neighbouring powder particles. It uses a simultaneous application of temperature and pressure, under a vacuum or inert gas environment to achieve high densification of the powder material. The heating rate is high (typically 1000˚C/min.) and the temperatures used are generally lower by 200˚C to 250˚C than temperatures used in conventional sintering [7] [8].

The SPS process is now applied extensively in the dielectric, piezoelectric, and thermoelectric fields [9] [10] [11] and in the processing of transparent ceramics [12] [13] [14] [15]. Significant work has also been done on the effect of the process on the microstructure and mechanical properties of composites [16]. However no significant work appears to have been done to explore the applicability of the process to the electrical contact materials manufacturing industry. Since the SPS technique is known to yield good densification of sintered products, it is likely to be satisfactory for electrical contact material production. There is indeed the possibility that the spark plasma sintered W-Cu and Mo-Cu compacts may have better properties, such as higher electrical conductivity, higher hardness and better wear resistance than both the LPS and Infiltration processes. This paper presents results of a comparative study on the electrical conductivity of LPS, Infiltration, and SPS-produced sintered compacts for electrical contact applications.

2. Experimental

2.1. Materials and Equipment

The materials used for this research work include powder specimens of tungsten, molybdenum, and copper, procured from vendors in the United Kingdom and the United States of America, while the equipment used include a turbular mixer, a Spark plasma sintering machine (Turbula system Shatz, Willy A. Bashoten AG, Maschinenfarrik, Switzerland) graphite moulds, a pneumatic single action press, steel dies, a controlled atmosphere sintering furnace, and an electrical conductivity measuring facility.

2.2. Experimental Methods

2.2.1. Production of Spark Plasma Sintered Specimens

Figure 1(a) and Figure 1(b) show the image of the Spark Plasma Sintering (SPS) machine used to produce the experimental specimens in the Engineering laboratories of the Tshwane University of Technology, Pretoria, South Africa. Seven metal powder blends were prepared having the compositions detailed in Table 1. Each blend was placed in a Turbular mixer and thoroughly tumbled for ten (10) hours. For the compaction and sintering operation, graphite dies of various diameters were available for use, and from these, dies of diameter 15 mm were selected. Specimens of diameter 15 mm and thickness 5 mm were thus produced for measurement of electrical and mechanical properties.

Table 1

Compositions of powder blends used in the SPS machine

W-Cu Samples	Mo-Cu Samples
1) W-20 wt% Cu	1) Mo-20 wt% Cu
2) W-30 wt% Cu	2) Mo-30 wt% Cu
3) W-40 wt% Cu	3) Mo-40 wt% Cu

Each powder mixture was placed in the dies between matching graphite punches and then placed in the SPS machine which combines the compaction process and the sintering at the same time in a vacuum environment. The SPS parameters determined for the present work were as follows:

Heating rate = 100˚C/minute.

Sintering temperature = 1000˚C.

Dwell time = 10 minutes.

Pressure = 40 MPa.

These parameters were used in the production of all the specimens. The cooling rate after the dwell time was also selected as 100˚C/minute.

For purposes of assessment and comparison of specimen properties, sintered W-Cu and Mo-Cu specimens were also produced using the contact infiltration and liquid phase sintering (LPS) processes.

2.2.2. Electrical Conductivity Measurements

The electrical conductivity of the specimens was measured using an electrical conductivity testing device based on the schematic diagram shown in Figure 2. From the figure, it is noted from the ammeter and voltmeter readings (currentI and voltage V), that the resistance R of the specimen is given by

R = V I ohms ( Ω ) (1)

Also,

R = ρ l A ( Ω ) (2)

where ρ = resistivity (Ω∙m)

l = length of specimen (m)

A = cross-sectional area of specimen (m²)

From (2), we have

ρ = R A l (3)

conductivity   σ = 1 ρ = l R A = I l V A ( Ω − 1 ⋅ m − 1 ) (4)

The conductivity values were recorded in terms of percent IACS (International Annealed copper standard), where the conductivity of commercial annealed copper at 20˚C which is 5.8001 × 10⁷ (Ω-m)⁻¹ or 5.8001 × 10⁷ Siemens/metre is defined to be 100% IACS.

The relative densities of all the specimens were measured.

3. Results and Discussion

3.1. Electrical Conductivity Results

The results obtained from electrical conductivity measurements are presented in Figure 3 and Figure 4 for the W-Cu and Mo-Cu composite compacts, respectively.

The Figures show clearly that the specimens produced by the Spark Plasma Sintering (SPS) process have substantially higher electrical conductivity than those produced by either the contact infiltration process or the liquid phase sintering (LPS) technique. This may be attributed to the very high level of densification (low level of porosity) in the specimens obtained by the SPS technique. Relative density test results showed that the relative densities of specimens produced by Liquid Phase Sintering ranged from 90% - 92% for W-Cu compacts with composition in the 20 wt% Cu to 40 wt% Cu range, and 88% to 90% for Mo-Cu compacts with copper in the same composition range. For the specimens produced by contact infiltration, the relative densities of the specimens ranged from 96.6% to 98% for the W-Cu specimens and 96.2% to 96.8% for the Mo-Cu specimens. On the other hand, all the specimens produced by the Spark Plasma Sintering process (with wt% copper within the same 20% - 40% range) had relative densities in the 99.1% to 100% range. The full densification often obtained from the SPS technique is a result of the three-stage process of plasma heating from the pulsed D.C. power supply, joule heating, and plastic deformation due to the simultaneous application of heat and compaction pressure.

The following points may also be noted from Figure 3 and Figure 4.

• The conductivities increase, as expected, with increase in copper content.

• The W-Cu specimens have higher conductivity than comparative Mo-Cu specimens. Fully dense pure tungsten and molybdenum materials have approximately equal electrical conductivities of 30.86% IACS. However, it is clear that for composites having equal weight percentages of Cu (e.g. W-20% Cu and Mo-20% Cu) the W-Cu composite will contain a larger quantity (higher volume %) of copper because of the higher density of tungsten as compared to molybdenum.

• The specimens produced by the infiltration process have, on average, conductivities that are slightly higher than those produced by the LPS process.

The values of electrical conductivity obtained in the present work are comparable with those reported in the literature for W-Cu, Mo-Cu, W-Ag and Mo-Ag specimens [17] [18] [19] [20] [21]. However, the values of conductivity obtained by the SPS technique in this work (for example 49.3% IACS and 46.8% IACS for W-40Cu and Mo-40Cu respectively) are higher than those reported. Comparative results in the literature give IACS values in the range of 40% - 43% for W-40 wt% Cu produced by infiltration.

3.2. Effect of Porosity on Electrical Conductivity

The porosity of engineering materials affects a wide range of their properties, such as their thermal, electrical, mechanical, acoustic and damping properties. There are several analytical models in the literature aimed at addressing some of the problems associated with the effects of porosity on properties [22] - [28]. Here, two model equations based on the Effective Medium Theory (EMT), are presented and compared with a third model provided by Montes et al. [29].

1) The Maxwell-Garnett Equation

The Maxwell-Garnett model (Maxwell (1998)) aims at calculating the effective conductivity of a mixture of two phases—a continuous or matrix phase, and a dispersed phase (e.g. pores). The equation is

σ e f − σ m σ e f + 2 σ m − p i σ i − σ m σ i + 2 σ m = 0 (5)

where σ e f = Effective conductivity.

σ m = Conductivity of the continuous matrix.

σ i = Conductivity of the spherical particle inclusions.

p i = Volume fraction of the inclusions.

2) The Bruggeman Approximation

This EMT model, [30] [31] [32] has been used to predict the electrical properties of two-phase composites. The model equation is as follows:

( 1 − p i ) σ m − σ e f σ m + σ e f + p i σ i − σ e f σ i + 2 σ e f = 0 (6)

where σ_ef, σ_m, σ_i and p_i are defined the same as for Equation (5) above.

The Bruggeman approximation has a broader applicability range than the Maxwell-Garnett equation which is ideal only for dilute composite media.

For porous materials, we may put σ i = σ p o r e s = 0 , and σ m = σ d = conductivity of the fully dense material. Thus Equations (5) and (6) above become:

σ e f = σ d ( 1 − p ) ( 1 + p 2 ) (Maxwell-Garnett) (7)

σ e f = σ d ( 2 − 3 p ) 2 (Bruggeman) (8)

where p = pore volume fraction, and σ_d = conductivity of the fully dense matrix material.

3) The Montes Model

The two models presented above assume the pores to be spherical and cannot therefore give very satisfactory results for the case of pores in powder metallurgy processed metallic composites. In this case, the pore sizes, pore distribution and actual pore geometry and orientation should be given due consideration. Considering these factors, Montes and his co-workers [25] arrived at the model equation given as

σ p = σ d ( 1 − φ φ 0 ) 2 1 − φ (9)

where σ_p = Conductivity of the porous sintered compact.

σ_d = Conductivity of the fully dense material.

φ = porosity of the sintered compact.

φ₀ = porosity of the vibrated starting powder mass.

Equation (9) is obtained based on a proper analysis of the effective path lengths and cross sectional areas for electron movement over a length L of a fully dense specimen (Figure 5(a)), and a porous specimen (Figure 5(b)).

The subscripts d andp for the path lengths (L_d and L_p), and areas (A_d and A_p) refer to the dense specimen and the porous specimen, respectively. From Figure 5, it may be noted that L_d = L; L_p > L_d; and A_p< A_d.

Equation (9) is obtained [25], based on theoretical expressions proposed for the relationships between A_p and A_d and between L_p and L_d for sintered powder products. These expressions are:

A p = A d ( 1 − φ φ 0 ) (10)

L p = L d [ 1 − φ 1 − φ φ 0 ] (11)

It may be noted here that the tap porosity φ₀ , which is the porosity of the starting powder mass after being vibrated, is very important. It is highly dependent on particle size, shape and distribution, and is therefore a paramount determinant of pore size and pore structure after compaction and sintering.

Assessment of Models Using Experimental Results

The three model Equations (Equations (7)-(9)) discussed above are assessed using experimental results obtained in this work for pure tungsten and pure molybdenum compacted and sintered to obtain sintered skeletons for contact infiltration purposes. The tap densities of the tungsten and molybdenum powders used for the work were 2.81 gm/cm³ and 3.05 gm/ cm³ respectively. Thus the relative densities of the vibrated powder mass were 2.81/19.3 = 0.146 for tungsten, and 3.05/10.2 = 0.30 for molybdenum (since densities of W and Mo are 19.3 gm/ cm³ and 10.2 gm/ cm³ respectively). Values of φ₀ for the vibrated starting powders of W and Mo are thus obtained as 0.854 and 0.70 respectively. Table 2 presents the values of the pore volume fractions, (φ) and electrical conductivity values σ_p predicted from the models. The values of electrical conductivity measured experimentally from the sintered W and Mo skeletons are compared with the values predicted from the models in Figure 6 (for pure tungsten) and Figure 7 (for pure molybdenum). The Figures show that at high values of porosity,

Table 2

Pore volume fractions (φ) and Electrical conductivity values (σ p ) Predicted from the models

PURE TUNGSTEN
Compaction Pressure (MPa)	% Porosity	Pore volume fraction, φ	1 − φ	initial pore vol. fraction of vibrated powder, φ0	φ φ 0 = φ R	σp (Montes Theory) (% IACS)	σp = σef Maxwell-Garnett (% IACS)	σp = σef Bruggeman (% IACS)
100	49.5	0.495	0.505	0.854	0.580	10.78	12.50	7.95
150	45.0	0.450	0.550	0.854	0.527	12.57	13.86	10.03
200	41.0	0.410	0.590	0.854	0.480	14.12	15.11	11.88
250	37.5	0.375	0.625	0.854	0.439	15.55	16.24	13.50
300	32.0	0.320	0.680	0.854	0.375	17.74	18.10	16.04
PURE MOLYBDENUM
100	42.0	0.420	0.580	0.70	0.600	8.51	14.80	11.42
150	37.0	0.370	0.630	0.70	0.529	10.87	16.41	13.73
200	34.0	0.340	0.660	0.70	0.486	12.34	17.41	15.12
250	28.0	0.280	0.720	0.70	0.400	15.43	19.49	17.90
300	25.0	0.250	0.750	0.70	0.357	17.00	20.57	19.29

there are significant differences in the conductivity values predicted by the models, but at low values of porosity, the differences become much smaller.

These results show that all three models may be depended upon for prediction of the electrical conductivity of sintered porous metals having relatively low levels of porosity (<20%). Since actual values of porosity in sintered compacts obtained using the LPS and infiltration techniques are generally lower than about 8%, the trends shown in Figure 6 and Figure 7 suggest that all three models are acceptable for providing estimates of electrical conductivity from porosity data. It may be noted that the predictions from the Montes model agree reasonably well with the conductivity values obtained experimentally, even at high levels of porosity. Therefore this model, which takes into account the tap density of the starting powder material, may be considered the best for making conductivity estimates even at relatively high levels of porosity.

4. Conclusions

From the results of this work, the following conclusions may be reached:

1) The Spark Plasma Sintering (SPS) process is capable of producing pore-free W-Cu and Mo-Cu composites, with relative densities in the range of 99% - 100%.

2) With the very high level of densification obtained by the SPS technique, W-Cu and Mo-Cu sintered compacts with relatively high electrical conductivity can easily be produced. For example, W-40 wt% Cu and Mo-40 wt% Cu with electrical conductivities of 49.3% IACS and 46.8% IACS respectively have been developed in this work. These values are substantially higher than those produced by other techniques.

3) From the results of this work, the SPS technique is recommended as the ideal process for producing wear-resistant and arc-erosion resistant composite materials for electrical contact applications.

4) The lower levels of electrical conductivity in specimens obtained by the current commercial techniques of infiltration and liquid phase sintering are mainly due to the residual porosities in specimens produced by these techniques.

5) Three models for predicting the conductivity of porous powder compacts the Maxwell-Garnett, Bruggeman, and Montes models have been assessed. It is found that the Montes model tends to give more accurate predictions because of the extra considerations given to pore size and shape as well as to pore distribution in the continuous matrix.

Conflicts of Interest

The authors declare no conflicts of interest regarding the publication of this paper.

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